Abstract
Excess molar volumes, V m E, and partial molar volumes, ↕ 2, have been determined for dilute aqueous solutions of 1-butanol, 1,2-butanediol, 2,3-butanediol, 1,3-butanediol, 1,4-butanediol, 1,2,4-butanetriol and 1,2,3,4-butanetetrol (erythritol) at 298.15 K, as a function of composition from density measurements. The limiting partial molar volumes, ↕ 2∞, of alcohols in aqueous solution are evaluated through extrapolation. Interactions of the different solutes with water are discussed in terms of the relationship among polar and non-polar groups on water structure and the effect of the position of hydroxyl groups in the molecule.
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George, J., Sastry, N.V.: Densities, dynamic viscosities, speeds of sound, and relative permittivities for water + alkanediols (propane-1,2- and -1,3-diol and butane-1,2-, -1,3-, -1,4-, and -2,3-diol) at different temperatures. J. Chem. Eng. Data 48, 1529–1539 (2003).
Trohalaki, S., Pachter, R., Cummings, J. R.: Modeling of fuel-system icing inhibitors. Energy Fuels 13, 992–998 (1999).
Pal, A., Kumar, S.: Volumetric properties of L-alanine, and L-valine in aqueous sucrose solutions at T = (288.15 and 308.15) K. J. Chem. Thermodyn. 37, 1085–1092 (2005).
Gekko, K.: Mechanism of polyol-induced protein stabilization: Solubility of amino acids and diglycine in aqueous polyol solutions. J. Biochem. 90, 1633–1641 (1981).
Back, J.F., Oakenfull, D., Smith, M.B.: Increased thermal stability of proteins in the presence of sugars and polyols. Biochem. 18, 5191–5196 (1979).
Palcez, B., Piekarski, H.: Enthalpies of solution of glycine in aqueous solution of 1,2 diols and glycerol at 25 ∘C. J. Solution Chem. 26, 621–629 (1997).
Lakshmi, T.S., Nandi, P.K.: Effects of sugar solutions on the activity coefficients of aromatic amino acids and their N-acethyl ethyl esters. J. Phys. Chem. 80, 249–252 (1998).
Uedaira, H., Uedaira, H.: The effect of sugars on the thermal denaturation of lysozyme. Bull. Chem. Soc. Jpn. 53, 2451–2455 (1980).
Frank, H.S., Evans, M., Free, W.: Volume and entropy in condensed systems. III. Entropy in binary liquid mixtures; Partial molal entropy in dilute solutions; Structure and thermodynamics in aqueous electrolytes. J. Chem. Phys. 13, 507–532 (1945).
Sakurai, M., Nakamura, K., Nitta, K.: Volumetric properties of dilute aqueous alcohol solutions at different temperatures. Bull. Chem. Soc. Jpn. 67, 1580–1587 (1994).
Fenclova, D., Perez-Casas, S.: Costas, M., Dohnal, V.: Partial molar heat capacities and partial molar volumes of all of the isomeric (C3 to C5) alkanols at infinite dilution in water at 298.15 K. J. Chem. Eng. Data 49, 1833–1838 (2004).
Hawrylak, B., Gracie, K., Palepu, R.: Thermodynamic properties of binary mixtures of butanediols with water. J. Solution Chem. 27, 17–31 (1998).
DiPaola, G., Belleau, B.: Polyol-water interactions. Apparent molal heat capacities and volumes of aqueous polyol solutions. Can J. Chem. 58, 3825–3830 (1977).
Zielenkiewicz, W., Poznanski, J.: Partial molar volumes of hydrophobic compounds—Insight into the solvation shell. Part I. J. Solution Chem. 27, 245–254 (1998).
Romero, C.M., Pez, M.: Thermodynamic properties of aqueous alcohol and polyol solutions. J. Therm. Anal. Calorim. 70, 263–267 (2002).
Hawrylak, B., Andrecyk, S., Gabriel, C., Gracie, K., Palepu, R.: Viscosity, surface tension, and refractive index measurements of mixtures of isomeric butanediols with water. J. Solution Chem. 27, 827–841 (1998).
Nakanishi, K.: Kato, N.: Maruyama, M.: Excess and partial volumes of some alcohol-water and glycol-water solutions. J. Phys. Chem. 71, 814–818 (1967).
Yang, C., Ma, P., Zhou, Q.: Excess molar volume, viscosity, and heat capacity for the mixtures of 1,4-butanediol + water at different temperatures. J. Chem. Eng. Data 49, 582–587 (2004).
Origlia-Luster, M.L., Patterson, B.A., Woolley, E.M.: Apparent molar volumes and apparent molar heat capacities of aqueous ethane-1,2-diol, propane-1,2-diol, and propane-1,3-diol at temperatures from 278.15 K to 393.15 K and at the pressure 0.35 MPa. J. Chem. Thermodyn. 34, 511–526 (2002).
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Romero, C.M., Páez, M.S. Volumetric Properties of Aqueous Binary Mixtures of 1-Butanol, Butanediols, 1,2,4-Butanetriol and Butanetetrol at 298.15 K. J Solution Chem 36, 237–245 (2007). https://doi.org/10.1007/s10953-006-9106-1
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DOI: https://doi.org/10.1007/s10953-006-9106-1