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Interactions in the Quaternary Systems H 2 O−Y(NO 3 ) 3 −La(NO 3 ) 3 −Pr(NO 3 ) 3 , H 2 O−Y(NO 3 ) 3 −La(NO 3 ) 3 −Nd(NO 3 ) 3 and H 2 O−Y(NO 3 ) 3 −Pr(NO 3 ) 3 −Nd(NO 3 ) 3 to Very High Concentrations

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Abstract

Isopiestic measurements have been carried out for the quaternary systems H2O−Y(NO3)3−La(NO3)3−Pr(NO3)3, H2O−Y(NO3)3−La(NO3)3−Nd(NO3)3 and H2O−Y(NO3)3−Pr(NO3)3−Nd(NO3)3 at 298.15 K to near saturation. The measurements can be represented by a modified Pitzer ion–interaction model extending to C (3) within the experimental uncertainty over the full concentration range. In addition, these systems obey the Zdanovskii-Stokes-Robinson model or partial ideal solution model within isopiestic accuracy, indicating zero solute-solute interchange energy, which is consistent with the nature of salts of the trivalent rare earth ions.

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Authors and Affiliations

  1. Department of Chemistry, Northeastern University, Shenyang, 110004, China

    Mei He & Zhi-Chang Wang

  2. Institute of Chemical Technology, Shenyang, 110142, China

    Mei He

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  1. Mei He
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He, M., Wang, ZC. Interactions in the Quaternary Systems H 2 O−Y(NO 3 ) 3 −La(NO 3 ) 3 −Pr(NO 3 ) 3 , H 2 O−Y(NO 3 ) 3 −La(NO 3 ) 3 −Nd(NO 3 ) 3 and H 2 O−Y(NO 3 ) 3 −Pr(NO 3 ) 3 −Nd(NO 3 ) 3 to Very High Concentrations. J Solution Chem 35, 1607–1619 (2006). https://doi.org/10.1007/s10953-006-9090-5

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