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Journal of Solution Chemistry

, Volume 35, Issue 12, pp 1621–1630 | Cite as

The Thermal Diffusion of Hydrogen Chloride in Water–Monoatomic Alcohol Mixtures at 298 K

  • V. N. Sokolov
  • L. P. Safonova
  • A. A. Pribochenko
Original Paper

Abstract

Standard entropies of the thermal diffusion transference of HCl, entropies of the moving H+ and Cl ions, and Soret coefficients of this electrolyte at 298 K were obtained from a thermoelectrochemical investigation of HCl in water + alcohol solvent systems. The thermoelectric powers of the silver/silver chloride and para-benzoquinone/hydroquinone thermocells have been measured. Effects of the mixed solvent composition and the nature of an alcohol on the thermal diffusion characteristics were discussed using the theories of De Bethune and Agar.

Keywords

Thermoelectrochemical systems Soret coefficients Thermal diffusion HCl Water + alcohol mixture 

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Copyright information

© Springer Science+Business Media, LLC 2006

Authors and Affiliations

  • V. N. Sokolov
    • 1
  • L. P. Safonova
    • 2
  • A. A. Pribochenko
    • 1
  1. 1.Ivanovo State University of Chemistry and TechnologyIvanovoRussia
  2. 2.Institute of Solution Chemistry of Russian Academy of SciencesIvanovoRussia

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