Abstract
Density data for dilute aqueous solutions of phenylacetic acid, benzene-1, 2-dicarboxylic acid (phtalic acid), benzene-1,2,4-tricarboxylic acid and 1,2,3-trihydroxy- benzene (pyrogallol) are presented together with the partial molar volumes at infinite dilution calculated from the experimental data. The measurements were performed at temperatures from T=298.15 K up to T=373.15 K and at three pressures up to 30 MPa. The data were obtained using a high-temperature, high-pressure flow vibrating-tube densimeter.
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Hnědkovský, L., Cibulka, I.: Group contributions for an estimation of partial molar volumes at infinite dilution for aqueous organic solutes at extended ranges of temperature and pressure. Int. J. Thermophys. 25, 387–395 (2004)
Hynek, V., Hnědkovský, L., Cibulka, I.: A new design of a vibrating-tube densimeter and partial molar volumes of phenol(aq) at temperatures from 298 to 573 K. J. Chem. Thermodyn. 29, 1237–1252 (1997)
Hnědkovský, L., Cibulka, I.: An automated vibrating-tube densimeter for measurements of small density differences in dilute aqueous solutions. Int. J. Thermophys. 25, 1135–1142 (2004)
Hill, P.G.: A unified fundamental equation for the thermodynamic properties of water. J. Phys. Chem. Ref. Data 19, 1233–1274 (1990)
Jacobsen, R. T., Stewart, R. B., Jahangiri, M.: Thermodynamic properties of nitrogen from the freezing line to 2000 K at pressures to 1000 MPa. J. Phys. Chem. Ref. Data 15, 735–909 (1986)
Hyněica, P., Hnědkovský, L., Cibulka, I.: Partial molar volumes of organic solutes in water. X. Benzene and toluene at temperatures T = 298 K to 573 K and at pressures up to 30 MPa. J. Chem. Thermodyn. 35, 1905–1915 (2003)
Jedelský, J., Hnědkovský, L., Hyněica, P., Cibulka, I.: Partial molar volumes of organic solutes in water. IV. Benzoic and hydroxybenzoic acids at temperatures T = (298 to 498) K and pressures up to 30 MPa. J. Chem. Thermodyn. 32, 1299–1310 (2000)
Jedelský, J., Hnědkovský, L., Cibulka, I.: Partial molar volumes of organic solutes in water. II. Dihydroxybenzenes at temperatures T = (298 to 498) K and pressures up to 30 MPa. J. Chem. Thermodyn. 31, 27–42 (1999)
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Lucie Střiteská, Lubomír Hnědkovský, and Ivan Cibulka: Partial molar volumes of phenylacetic acid and several polysubstituted benzenes at infinite dilution in water at temperatures T = 298 K to 373 K and at pressures up to 30 MPa.
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Stříteská, L., Hnědkovský, L. & Cibulka, I. Partial Molar Volumes of Phenylacetic Acid and Several Polysubstituted Benzenes at Infinite Dilution in Water at Temperatures T = 298 to 373 K and at Pressures up to 30 MPa. J Solution Chem 35, 1029–1036 (2006). https://doi.org/10.1007/s10953-006-9045-x
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DOI: https://doi.org/10.1007/s10953-006-9045-x