Skip to main content
Log in

Liquid–Liquid Equilibria of Oxygenate Fuel Additives with Water at 298.15 K: Ternary and Quaternary Aqueous Systems of Diisopropyl Ether and Hydrocarbons with 2-Propanol

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Experimental tie-line data were determined for one ternary system, water + diisopropyl ether + n-heptane and two quaternary systems, water + diisopropyl ether + 2-propanol + n-heptane or toluene at 298.15 K and ambient pressure. The experimental liquid–liquid equilibrium data were successfully correlated using a modified UNIQUAC model with ternary and quaternary mixture parameters, in addition to the binary ones. The calculated results were also compared with those obtained from an extended UNIQUAC model of Nagata [Fluid Phase Equilib. 54, 191 (1990)].

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. K. Tamura, Y. Chen, K. Tada, T. Yamada, and I. Nagata, J. Solution Chem. 29, 463 (2000).

    Article  CAS  Google Scholar 

  2. I. Nagata, Fluid Phase Equilib. 54, 191 (1990).

    Article  CAS  Google Scholar 

  3. V. V. Udovenko and T. F. Mazanko, Zh. Fiz. Khim. 41, 1615 (1967).

    CAS  Google Scholar 

  4. C. R. Chamorro, J. J. Segovia, M. C. MartÍn, and M. A. Villamañán, J. Chem. Thernodyn. 34, 13 (2002).

    CAS  Google Scholar 

  5. S. V. Vijayaraghavan, P. K. Deshpande, and N. R. Kuloor, J. Chem. Eng. Data 12, 15 (1967).

    CAS  Google Scholar 

  6. J. Wisniak, B. Yardeni, T. Sling, and H. Segura, J. Chem. Eng. Data 46, 223 (2001).

    Article  CAS  Google Scholar 

  7. R. Barraza and J. Edwards, Monatsh. Chem. 112, 925 (1981).

    Article  CAS  Google Scholar 

  8. S. J. Ashcroft, A. D. Claylon, and R. B. Shearn, J. Chem. Eng. Data 24, 195 (1979).

    Article  CAS  Google Scholar 

  9. A. Arce, A. Marchiaro, O. Rodriguez, and A. Soto, J. Chem. Eng. Data 47, 529 (2002).

    Article  CAS  Google Scholar 

  10. J. M. Sö rensen and W. Arlt, Liquid–Liquid Equilibrium Data Collection, Vol. V, Part 1 (DECHEMA, Frankfurt am Main, 1979), 470 pp.

  11. F. Ruiz, D. Prats, and V. Gomis, J. Chem. Eng. Data 30, 412 (1985).

    Article  CAS  Google Scholar 

  12. A. Arce, A. Arce Jr., J. MartÍnez-Ageitos, E. Rodil, O. RodrÍguez, and A. Soto, Fluid Phase Equilib. 170, 113 (2000).

    Article  CAS  Google Scholar 

  13. E. R. Washburn and A. E. Beguin, J. Am. Chem. Soc. 62, 579 (1940).

    CAS  Google Scholar 

  14. A. I. Vorobeva and M. K. H. Karapetyants, Zh. Fiz. Khim. 41, 1984 (1967).

    CAS  Google Scholar 

  15. Z. J. Pan, Y. Chen, Y. H. Dong, R. Q. Li, and Y. Tang, J. Jinan Univ. Nat. Sci. Med. Ed. 25, 609 (2004).

    CAS  Google Scholar 

  16. J. Gmehling, J. Li, and M. Schiller, Ind. Eng. Chem. Res. 32, 178 (1993).

    Article  CAS  Google Scholar 

  17. J. M. Prausnitz, T. F. Anderson, E. A. Grens, C. A. Eckert, R. Hsieh, and J. P. O'Connell, Computer Calculations for Multicomponent Vapor–Liquid and Liquid–Liquid Equilibria (Prentice-Hall, Englewood Cliffs, NJ, 1980).

    Google Scholar 

  18. K. Tamura, Y. Chen, and T. Yamada, J. Solution Chem. 30, 291 (2001).

    Article  CAS  Google Scholar 

  19. J. A. Riddick, W. B. Bunger, and T. K. Sakano, Organic Solvents, 4th edn. (Wiley-Interscience, New York, 1986).

    Google Scholar 

  20. C. F. Spencer and R. P. Danner, J. Chem. Eng. Data 17, 236 (1972).

    Article  CAS  Google Scholar 

  21. J. G. Hayden and J. P. O'Connell, Ind. Eng. Chem. Process. Des. Dev. 14, 209 (1975).

    Article  CAS  Google Scholar 

  22. J. A. Nelder and P. Mead, Comput. J. 7, 308 (1965).

    Google Scholar 

  23. E. A. Macedo and P. Rasmussen, Liquid–Liquid Equilibrium Data Collection, Suppl. 1. Vol. V, Part 4 (DECHEMA, Frankfurt am Main, 1987).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yao Chen.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, Y., Dong, Y. Liquid–Liquid Equilibria of Oxygenate Fuel Additives with Water at 298.15 K: Ternary and Quaternary Aqueous Systems of Diisopropyl Ether and Hydrocarbons with 2-Propanol. J Solution Chem 34, 1445–1457 (2005). https://doi.org/10.1007/s10953-005-8517-8

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10953-005-8517-8

Keywords

Navigation