Abstract
The diffusion coefficient of Tl+ ions, the standard potential, the size factor of the activated complex, and the standard rate constant of the overall reaction Tl(I)/Tl(Hg) in aqueous mixtures of acetone, methanol, acetonitrile, and dimethylformamide are related to parameters representing the composition, polarity, electron pair, and hydrogen-bond donor ability of these mixtures. The dependencies on mixture composition, and the linear and multilinear correlation with solvatochromic parameters are interpreted by assuming a heterosolvation effect in combination with a two-step ion transfer – ion adsorption mechanism.
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Anastopoulos, A.G., Latsinoglou, T. Correlation of Kinetic and Thermodynamic Quantities of Tl(I)/Tl(Hg) Electroreduction with Parameters of Binary Mixtures of Water with Acetone, Acetonitrile, Methanol, and N,N-dimethylformamide. J Solution Chem 34, 1341–1356 (2005). https://doi.org/10.1007/s10953-005-8507-x
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DOI: https://doi.org/10.1007/s10953-005-8507-x