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On Hysteresis and Magnetocaloric Effect in CoS\(_{1.76}\)Se\(_{0.24}\)

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Abstract

The path dependence of the magnetocaloric effect (MCE) in CoS\(_{1.76}\)Se\(_{0.24}\) has been studied. A field-induced paramagnetic (PM)-ferromagnetic (FM) transition results in 4.6 J/kg-K peak value of isothermal entropy change (\(\Delta\)S\(_{th}\)) for 90 kOe field change. Above 10 K, the temperature dependence of \(\Delta\)S\(_{th}\) calculated from the forward curve (0 kOe–90 kOe) and that calculated from the reverse curve (90 kOe–0 kOe) are found to be similar, whereas at lower temperature, contrasting behaviour is observed due to the kinetic arrest of first-order magnetic transition.

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References

  1. Franco, V., Blázquez, J.S., Ingale, B., Conde, A.: The magnetocaloric effect and magnetic refrigeration near room temperature: materials and models. Annu. Rev. Mater. Res. 42, 305 (2012)

    Article  ADS  Google Scholar 

  2. Franco, V., Blázquez, J.S., Ipus, J.J., Law, J.Y., Moreno-Ramírez, L.M., Conde, A.: Magnetocaloric effect: from materials research to refrigeration devices. Prog. Mater Sci. 93, 112 (2018)

    Article  Google Scholar 

  3. Raghu Ram, N., Prakash, U., Naresh, M., Suresh Kumar, N., Sofi Sarmash, T., Subbarao, T., Jeevan Kumar, R., Ranjith Kumar, G., Chandra Babu Naidu, K.: Review on magnetocaloric effect and materials. J. Supercond. Novel Magn. 31, 1971 (2018)

    Article  Google Scholar 

  4. Dan’kov, S.Y., Tishin, A.M., Pecharsky, V.K., Gschneidner, K.A.: Magnetic phase transitions and the magnetothermal properties of gadolinium. Phys. Rev. B 57, 3478 (1998)

    Article  ADS  Google Scholar 

  5. Chirkova, A., Skokov, K., Schultz, L., Baranov, N., Gutfleisch, O., Woodcock, T.G.: Giant adiabatic temperature change in FeRh alloys evidenced by direct measurements under cyclic conditions. Acta Mater. 106, 15 (2016)

    Article  ADS  Google Scholar 

  6. Joshi, R., Karmakar, S., Kumar, K., Gupta, M., Rawat, R.: Room temperature giant magnetocaloric effect in Pd doped FeRh and the effect of martensitic transition. J. Appl. Phys. 133(17) (2023)

  7. Pecharsky, V.K., Gschneidner, K.A., Jr.: Giant magnetocaloric effect in Gd5Si2Ge2. Phys. Rev. Lett. 78, 4494 (1997)

    Article  ADS  Google Scholar 

  8. Valiev, E.Z., Kazantsev, V.A.: Magnetocaloric effect in La(FexSi1−x)13 ferromagnets. J. Exp. Theor. Phys. 113, 1000 (2011)

    Article  ADS  Google Scholar 

  9. Wada, H., Tanabe, Y.: Giant magnetocaloric effect of MnAs1-xSbx. Appl. Phys. Lett. 79(20), 3302 (2001)

    Article  ADS  Google Scholar 

  10. Gutfleisch, O., Gottschall, T., Fries, M., Benke, D., Radulov, I., Skokov, K.P., Wende, H., Gruner, M., Acet, M., Entel, P., et al.: Mastering hysteresis in magnetocaloric materials. Philos. Trans. R. Soc. A Math. Phys. Eng. Sci. 374(2074), 20150308 (2016)

    Article  ADS  Google Scholar 

  11. Gottschall, T., Skokov, K.P., Fries, M., Taubel, A., Radulov, I., Scheibel, F., Benke, D., Riegg, S., Gutfleisch, O.: Making a cool choice: the materials library of magnetic refrigeration. Adv. Energy Mater. 9(34), 1901322 (2019)

    Article  Google Scholar 

  12. Stern-Taulats, E., Planes, A., Lloveras, P., Barrio, M., Tamarit, J.-L., Pramanick, S., Majumdar, S., Frontera, C., Mañosa, L.: Barocaloric and magnetocaloric effects in Fe49Rh51. Phys. Rev. B 89, 214105 (2014)

    Article  ADS  Google Scholar 

  13. Aliev, A.M., Batdalov, A.B., Khanov, L.N., Kamantsev, A.P., Koledov, V.V., Mashirov, A.V., Shavrov, V.G., Grechishkin, R.M., Kaul, A.R., Sampath, V.: Reversible magnetocaloric effect in materials with first order phase transitions in cyclic magnetic fields: Fe48Rh52 and Sm0.6Sr0.4MnO3. Appl. Phys. Lett. 109(20), (2016)

  14. Chirkova, A.M., Skokov, K.P., Skourski, Y., Scheibel, F., Karpenkov, A.Y., Volegov, A.S., Baranov, N.V., Nielsch, K., Schultz, L., Müller, K.-H., Woodcock, T.G., Gutfleisch, O.: Magnetocaloric properties and specifics of the hysteresis at the first-order metamagnetic transition in Ni-doped FeRh. Phys. Rev. Mater. 5, 064412 (2021)

    Article  Google Scholar 

  15. Gràcia-Condal, A., Stern-Taulats, E., Planes, A., Mañosa, L.: Caloric response of Fe49Rh51 subjected to uniaxial load and magnetic field. Phys. Rev. Mater. 2, 084413 (2018)

    Article  Google Scholar 

  16. Kushwaha, P., Bag, P., Rawat, R., Chaddah, P.: First-order antiferro–ferromagnetic transition in Fe49(Rh0.93Pd0.07)51 under simultaneous application of magnetic field and external pressure. J. Phys. Condens. Matter 24(9), 096005 (2012)

    Article  ADS  Google Scholar 

  17. Kushwaha, P., Rawat, R., Chaddah, P.: Metastability in the ferrimagnetic–antiferromagnetic phase transition in Co substituted Mn2Sb. J. Phys. Condens. Matter 20(2), 022204 (2007)

    Article  ADS  Google Scholar 

  18. Adachi, K., Matsui, M., Kawai, M.: Further investigations on magnetic properties of Co(SxSe1-x)2,(0 ≤  x ≤  1). J. Phys. Soc. Jpn. 46(5), 1474 (1979)

    Article  ADS  Google Scholar 

  19. Krill, G., Panissod, P., Lahrichi, M., Lapierre-Ravet, M.F.: Magnetic properties of the CoS2-xSex compounds. I. concentration and temperature effects on the ‘metamagnetic’ transition. J. Phys. C: Solid State Phys. 12(20), 4269 (1979)

    Article  ADS  Google Scholar 

  20. Wada, H., Mitsuda, A., Tanaka, K.: Magnetic entropy change of itinerant electron metamagnetic system Co(S1-xSex)2. Phys. Rev. B 74, 214407 (2006)

    Article  ADS  Google Scholar 

  21. Goto, T., Shindo, Y., Takahashi, H., Ogawa, S.: Magnetic properties of the itinerant metamagnetic system Co(S1-xSex)2 under high magnetic fields and high pressure. Phys. Rev. B 56(21), 14019 (1997)

    Article  ADS  Google Scholar 

  22. Mishra, S.K., Rawat, R.: Evidence of kinetic arrest in Se doped CoS2. Solid State Commun. 244, 33 (2016)

    Article  ADS  Google Scholar 

  23. Rawat, R., Mukherjee, K., Kumar, K., Banerjee, A., Chaddah, P.: Anomalous first-order transition in Nd0.5Sr0.5MnO3: an interplay between kinetic arrest and thermodynamic transitions. J. Phys. Condens. Matter 19(25), 256211 (2007)

    Article  ADS  Google Scholar 

  24. Johnson, V., Wold, A.: Crystal growth and magnetic properties of compositions in the CoS2: CoSe2 system. J. Solid State Chem. 2(2), 209 (1970)

    Article  ADS  Google Scholar 

  25. Bag, P., Rawat, R., Chaddah, P., Babu, P.D., Siruguri, V.: Unconventional thermal effects across first-order magnetic transition in the Ta-doped HfFe2 intermetallic. Phys. Rev. B 93, 014416 (2016)

    Article  ADS  Google Scholar 

  26. Raychaudhuri, A.K., Guha, A., Das, I., Rawat, R., Rao, C.N.R.: Specific heat of single-crystalline Pr0.63Ca0.37MnO3 in the presence of a magnetic field. Phys. Rev. B 64, 165111 (2001)

    Article  ADS  Google Scholar 

  27. Gschneidner, K.A., Jr., Pecharsky, V.K., Fort, D.: Novel thermal effects at the first order magnetic phase transition in erbium, and a comparison with dysprosium. Phys. Rev. Lett. 78(22), 4281 (1997)

    Article  ADS  Google Scholar 

  28. Singh, V., Kumar, R., Bag, P., Rawat, R., Kushwaha, P.: Magnetocaloric effect and magnetoresistance correlation in Ge-doped Mn2Sb. Mater. Res. Express 1(4), 046101 (2014)

    Article  ADS  Google Scholar 

  29. Imry, Y., Wortis, M.: Influence of quenched impurities on first-order phase transitions. Phys. Rev. B 19, 3580 (1979)

    Article  ADS  Google Scholar 

  30. Roy, S.B., Perkins, G.K., Chattopadhyay, M.K., Nigam, A.K., Sokhey, K.J.S., Chaddah, P., Caplin, A.D., Cohen, L.F.: First order magnetic transition in doped CeFe2 alloys: phase coexistence and metastability. Phys. Rev. Lett. 92, 147203 (2004)

    Article  ADS  Google Scholar 

  31. Rawat, R., Kushwaha, P., Mishra, D.K., Sathe, V.G.: Direct visualization of first-order magnetic transition in La5/8-yPryCa3/8MnO3 (y = 0.45) thin films. Phys. Rev. B 87(6), 064412 (2013)

    Article  ADS  Google Scholar 

  32. Chaddah P.: Necessary and sufficient condition for a disorder-broadened transition to be identified as 1st order. Preprint at http://arxiv.org/abs/1405.1162 (2014)

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Acknowledgements

We thank Mukul Gupta and Layanta Behera for the XRD measurements. M. P. Saravanan and cryogenic group are acknowledged for cryogen.

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S.K. synthesized samples, performed measurements, data analysis, and wrote the original draft manuscript, R.J. helped in measurements and data analysis, K.K. helped in data collection and insights, and R.R. supervised, writing the final manuscript.

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Correspondence to Suman Karmakar.

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Karmakar, S., Joshi, R., Kumar, K. et al. On Hysteresis and Magnetocaloric Effect in CoS\(_{1.76}\)Se\(_{0.24}\). J Supercond Nov Magn (2024). https://doi.org/10.1007/s10948-024-06755-0

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