Abstract
The path dependence of the magnetocaloric effect (MCE) in CoS\(_{1.76}\)Se\(_{0.24}\) has been studied. A field-induced paramagnetic (PM)-ferromagnetic (FM) transition results in 4.6 J/kg-K peak value of isothermal entropy change (\(\Delta\)S\(_{th}\)) for 90 kOe field change. Above 10 K, the temperature dependence of \(\Delta\)S\(_{th}\) calculated from the forward curve (0 kOe–90 kOe) and that calculated from the reverse curve (90 kOe–0 kOe) are found to be similar, whereas at lower temperature, contrasting behaviour is observed due to the kinetic arrest of first-order magnetic transition.
Similar content being viewed by others
Data Availability
No datasets were generated or analysed during the current study.
References
Franco, V., Blázquez, J.S., Ingale, B., Conde, A.: The magnetocaloric effect and magnetic refrigeration near room temperature: materials and models. Annu. Rev. Mater. Res. 42, 305 (2012)
Franco, V., Blázquez, J.S., Ipus, J.J., Law, J.Y., Moreno-Ramírez, L.M., Conde, A.: Magnetocaloric effect: from materials research to refrigeration devices. Prog. Mater Sci. 93, 112 (2018)
Raghu Ram, N., Prakash, U., Naresh, M., Suresh Kumar, N., Sofi Sarmash, T., Subbarao, T., Jeevan Kumar, R., Ranjith Kumar, G., Chandra Babu Naidu, K.: Review on magnetocaloric effect and materials. J. Supercond. Novel Magn. 31, 1971 (2018)
Dan’kov, S.Y., Tishin, A.M., Pecharsky, V.K., Gschneidner, K.A.: Magnetic phase transitions and the magnetothermal properties of gadolinium. Phys. Rev. B 57, 3478 (1998)
Chirkova, A., Skokov, K., Schultz, L., Baranov, N., Gutfleisch, O., Woodcock, T.G.: Giant adiabatic temperature change in FeRh alloys evidenced by direct measurements under cyclic conditions. Acta Mater. 106, 15 (2016)
Joshi, R., Karmakar, S., Kumar, K., Gupta, M., Rawat, R.: Room temperature giant magnetocaloric effect in Pd doped FeRh and the effect of martensitic transition. J. Appl. Phys. 133(17) (2023)
Pecharsky, V.K., Gschneidner, K.A., Jr.: Giant magnetocaloric effect in Gd5Si2Ge2. Phys. Rev. Lett. 78, 4494 (1997)
Valiev, E.Z., Kazantsev, V.A.: Magnetocaloric effect in La(FexSi1−x)13 ferromagnets. J. Exp. Theor. Phys. 113, 1000 (2011)
Wada, H., Tanabe, Y.: Giant magnetocaloric effect of MnAs1-xSbx. Appl. Phys. Lett. 79(20), 3302 (2001)
Gutfleisch, O., Gottschall, T., Fries, M., Benke, D., Radulov, I., Skokov, K.P., Wende, H., Gruner, M., Acet, M., Entel, P., et al.: Mastering hysteresis in magnetocaloric materials. Philos. Trans. R. Soc. A Math. Phys. Eng. Sci. 374(2074), 20150308 (2016)
Gottschall, T., Skokov, K.P., Fries, M., Taubel, A., Radulov, I., Scheibel, F., Benke, D., Riegg, S., Gutfleisch, O.: Making a cool choice: the materials library of magnetic refrigeration. Adv. Energy Mater. 9(34), 1901322 (2019)
Stern-Taulats, E., Planes, A., Lloveras, P., Barrio, M., Tamarit, J.-L., Pramanick, S., Majumdar, S., Frontera, C., Mañosa, L.: Barocaloric and magnetocaloric effects in Fe49Rh51. Phys. Rev. B 89, 214105 (2014)
Aliev, A.M., Batdalov, A.B., Khanov, L.N., Kamantsev, A.P., Koledov, V.V., Mashirov, A.V., Shavrov, V.G., Grechishkin, R.M., Kaul, A.R., Sampath, V.: Reversible magnetocaloric effect in materials with first order phase transitions in cyclic magnetic fields: Fe48Rh52 and Sm0.6Sr0.4MnO3. Appl. Phys. Lett. 109(20), (2016)
Chirkova, A.M., Skokov, K.P., Skourski, Y., Scheibel, F., Karpenkov, A.Y., Volegov, A.S., Baranov, N.V., Nielsch, K., Schultz, L., Müller, K.-H., Woodcock, T.G., Gutfleisch, O.: Magnetocaloric properties and specifics of the hysteresis at the first-order metamagnetic transition in Ni-doped FeRh. Phys. Rev. Mater. 5, 064412 (2021)
Gràcia-Condal, A., Stern-Taulats, E., Planes, A., Mañosa, L.: Caloric response of Fe49Rh51 subjected to uniaxial load and magnetic field. Phys. Rev. Mater. 2, 084413 (2018)
Kushwaha, P., Bag, P., Rawat, R., Chaddah, P.: First-order antiferro–ferromagnetic transition in Fe49(Rh0.93Pd0.07)51 under simultaneous application of magnetic field and external pressure. J. Phys. Condens. Matter 24(9), 096005 (2012)
Kushwaha, P., Rawat, R., Chaddah, P.: Metastability in the ferrimagnetic–antiferromagnetic phase transition in Co substituted Mn2Sb. J. Phys. Condens. Matter 20(2), 022204 (2007)
Adachi, K., Matsui, M., Kawai, M.: Further investigations on magnetic properties of Co(SxSe1-x)2,(0 ≤ x ≤ 1). J. Phys. Soc. Jpn. 46(5), 1474 (1979)
Krill, G., Panissod, P., Lahrichi, M., Lapierre-Ravet, M.F.: Magnetic properties of the CoS2-xSex compounds. I. concentration and temperature effects on the ‘metamagnetic’ transition. J. Phys. C: Solid State Phys. 12(20), 4269 (1979)
Wada, H., Mitsuda, A., Tanaka, K.: Magnetic entropy change of itinerant electron metamagnetic system Co(S1-xSex)2. Phys. Rev. B 74, 214407 (2006)
Goto, T., Shindo, Y., Takahashi, H., Ogawa, S.: Magnetic properties of the itinerant metamagnetic system Co(S1-xSex)2 under high magnetic fields and high pressure. Phys. Rev. B 56(21), 14019 (1997)
Mishra, S.K., Rawat, R.: Evidence of kinetic arrest in Se doped CoS2. Solid State Commun. 244, 33 (2016)
Rawat, R., Mukherjee, K., Kumar, K., Banerjee, A., Chaddah, P.: Anomalous first-order transition in Nd0.5Sr0.5MnO3: an interplay between kinetic arrest and thermodynamic transitions. J. Phys. Condens. Matter 19(25), 256211 (2007)
Johnson, V., Wold, A.: Crystal growth and magnetic properties of compositions in the CoS2: CoSe2 system. J. Solid State Chem. 2(2), 209 (1970)
Bag, P., Rawat, R., Chaddah, P., Babu, P.D., Siruguri, V.: Unconventional thermal effects across first-order magnetic transition in the Ta-doped HfFe2 intermetallic. Phys. Rev. B 93, 014416 (2016)
Raychaudhuri, A.K., Guha, A., Das, I., Rawat, R., Rao, C.N.R.: Specific heat of single-crystalline Pr0.63Ca0.37MnO3 in the presence of a magnetic field. Phys. Rev. B 64, 165111 (2001)
Gschneidner, K.A., Jr., Pecharsky, V.K., Fort, D.: Novel thermal effects at the first order magnetic phase transition in erbium, and a comparison with dysprosium. Phys. Rev. Lett. 78(22), 4281 (1997)
Singh, V., Kumar, R., Bag, P., Rawat, R., Kushwaha, P.: Magnetocaloric effect and magnetoresistance correlation in Ge-doped Mn2Sb. Mater. Res. Express 1(4), 046101 (2014)
Imry, Y., Wortis, M.: Influence of quenched impurities on first-order phase transitions. Phys. Rev. B 19, 3580 (1979)
Roy, S.B., Perkins, G.K., Chattopadhyay, M.K., Nigam, A.K., Sokhey, K.J.S., Chaddah, P., Caplin, A.D., Cohen, L.F.: First order magnetic transition in doped CeFe2 alloys: phase coexistence and metastability. Phys. Rev. Lett. 92, 147203 (2004)
Rawat, R., Kushwaha, P., Mishra, D.K., Sathe, V.G.: Direct visualization of first-order magnetic transition in La5/8-yPryCa3/8MnO3 (y = 0.45) thin films. Phys. Rev. B 87(6), 064412 (2013)
Chaddah P.: Necessary and sufficient condition for a disorder-broadened transition to be identified as 1st order. Preprint at http://arxiv.org/abs/1405.1162 (2014)
Acknowledgements
We thank Mukul Gupta and Layanta Behera for the XRD measurements. M. P. Saravanan and cryogenic group are acknowledged for cryogen.
Author information
Authors and Affiliations
Contributions
S.K. synthesized samples, performed measurements, data analysis, and wrote the original draft manuscript, R.J. helped in measurements and data analysis, K.K. helped in data collection and insights, and R.R. supervised, writing the final manuscript.
Corresponding author
Ethics declarations
Competing Interests
The authors declare no competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Karmakar, S., Joshi, R., Kumar, K. et al. On Hysteresis and Magnetocaloric Effect in CoS\(_{1.76}\)Se\(_{0.24}\). J Supercond Nov Magn (2024). https://doi.org/10.1007/s10948-024-06755-0
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10948-024-06755-0