Abstract
Gilbert damping is one of the critical parameters in magnetic thin films for developing low-power spintronic devices, and \({\mathrm{Co}}_{40}{\mathrm{Fe}}_{40}{\mathrm{B}}_{20}\) (CFB) is one of the sought-after materials in this regard. Here, we report the effect of annealing on the structural, magnetization reversal, and spin dynamics of CFB thin films. X-ray diffraction results show that as-deposited films are amorphous and retain their nature upon annealing up to 350 °C. Magnetization reversal results exhibit anisotropic behavior in both as-deposited and annealed samples. The random anisotropy model explains the change in coercivity in the transverse axis with respect to the longitudinal axis for CFB annealed at 350 °C. Broadband ferromagnetic resonance spectra reveal that the damping parameter decreases with increasing annealing temperature. Ultra-low damping of 0.004 is obtained with annealing at 350 °C. Surface topographical images from atomic force microscopy are rewarded for supporting the observed variation of the damping constant. Our systematic study gives an insight into CFB magnetization reversal and dynamics for developing ultra-low damping magnetic thin films via annealing.
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Žutić, I., Fabian, J., Das Sarma, S.: Spintronics: fundamentals and applications. Rev. Mod. Phys. 76, 323–410 (2004). https://doi.org/10.1103/RevModPhys.76.323
Hoffmann, A., Bader, S.D.: Opportunities at the frontiers of spintronics. Phys. Rev. Appl. 4, 047001 (2015). https://doi.org/10.1103/PhysRevApplied.4.047001
Kittel, C.: On the theory of ferromagnetic resonance absorption. Phys. Rev. 73, 155–161 (1948). https://doi.org/10.1103/PhysRev.73.155
Suhl, H.: Theory of the magnetic damping constant. IEEE Trans. Magn. 34, 1834–1838 (1998). https://doi.org/10.1109/20.706720
Tsoi, M., Jansen, A.G.M., Bass, J., Chiang, W.-C., Seck, M., Tsoi, V., Wyder, P.: Excitation of a magnetic multilayer by an electric current. Phys. Rev. Lett. 80, 4281–4284 (1998). https://doi.org/10.1103/PhysRevLett.80.4281
Slonczewski, J.: Excitation of spin waves by an electric current. J. Magn. Magn. Mater. 195, L261–L268 (1999). https://doi.org/10.1016/S0304-8853(99)00043-8
Kittel, C.: Theory of the dispersion of magnetic permeability in ferromagnetic materials at microwave frequencies. Phys. Rev. 70, 281–290 (1946). https://doi.org/10.1103/PhysRev.70.281
Sparks, M., Loudon, R., Kittel, C.: Ferromagnetic relaxation. I. Theory of the relaxation of the uniform precession and the degenerate spectrum in insulators at low temperatures. Phys. Rev. 122, 791–803 (1961). https://doi.org/10.1103/PhysRev.122.791
Hurben, M.J., Patton, C.E.: Theory of two magnon scattering microwave relaxation and ferromagnetic resonance linewidth in magnetic thin films. J. Appl. Phys. 83, 4344–4365 (1998). https://doi.org/10.1063/1.367194
Platow, W., Anisimov, A.N., Dunifer, G.L., Farle, M., Baberschke, K.: Correlations between ferromagnetic-resonance linewidths and sample quality in the study of metallic ultrathin films. Phys. Rev. B. 58, 5611–5621 (1998). https://doi.org/10.1103/PhysRevB.58.5611
Yang, A., Imrane, H., Lou, J., Kirkland, J., Vittoria, C., Sun, N., Harris, V.G.: Effects of boron addition to the atomic structure and soft magnetic properties of FeCoB films. J. Appl. Phys. 103, 07E736 (2008). https://doi.org/10.1063/1.2838226
Wang, Y.-H., Chen, W.-C., Yang, S.-Y., Shen, K.-H., Park, C., Kao, M.-J., Tsai, M.-J.: Interfacial and annealing effects on magnetic properties of CoFeB thin films. J. Appl. Phys. 99, 08M307 (2006). https://doi.org/10.1063/1.2176108
Teixeira, J.M., Ventura, J., Carpinteiro, F., Araujo, J.P., Sousa, J.B., Wisniowski, P., Freitas, P.P.: The effect of pinhole formation/growth on the tunnel magnetoresistance of MgO-based magnetic tunnel junctions. J. Appl. Phys. 106, 073707 (2009). https://doi.org/10.1063/1.3236512
Dimopoulos, T., Gieres, G., Wecker, J., Wiese, N., Sacher, M.D.: Thermal annealing of junctions with amorphous and polycrystalline ferromagnetic electrodes. J. Appl. Phys. 96, 6382–6386 (2004). https://doi.org/10.1063/1.1808899
Ikeda, S., Koizumi, R., Sato, H., Yamanouchi, M., Miura, K., Mizunuma, K., Gan, H., Matsukura, F., Ohno, H.: Boron composition dependence of magnetic anisotropy and tunnel magnetoresistance in MgO/CoFe(B) based stack structures. IEEE Trans. Magn. 48, 3829–3832 (2012). https://doi.org/10.1109/TMAG.2012.2203588
Miyajima, T., Ibusuki, T., Umehara, S., Sato, M., Eguchi, S., Tsukada, M., Kataoka, Y.: Transmission electron microscopy study on the crystallization and boron distribution of CoFeB/MgO/CoFeB magnetic tunnel junctions with various capping layers. Appl. Phys. Lett. 94, 122501 (2009). https://doi.org/10.1063/1.3106624
Wang, Z., Saito, M., McKenna, K.P., Fukami, S., Sato, H., Ikeda, S., Ohno, H., Ikuhara, Y.: Atomic-scale structure and local chemistry of CoFeB–MgO magnetic tunnel junctions. Nano Lett. 16, 1530–1536 (2016). https://doi.org/10.1021/acs.nanolett.5b03627
Cardoso, S., Cavaco, C., Ferreira, R., Pereira, L., Rickart, M., Freitas, P.P., Franco, N., Gouveia, J., Barradas, N.P.: Characterization of CoFeB electrodes for tunnel junctions. J. Appl. Phys. 97, 10C916 (2005). https://doi.org/10.1063/1.1853833
Bilzer, C., Devolder, T., Kim, J.-V., Counil, G., Chappert, C., Cardoso, S., Freitas, P.P.: Study of the dynamic magnetic properties of soft CoFeB films. J. Appl. Phys. 100, 053903 (2006). https://doi.org/10.1063/1.2337165
Conca, A., Greser, J., Sebastian, T., Klingler, S., Obry, B., Leven, B., Hillebrands, B.: Low spin-wave damping in amorphous Co 40 Fe 40 B 20 thin films. J. Appl. Phys. 113, 213909 (2013). https://doi.org/10.1063/1.4808462
Conca, A., Papaioannou, E.T., Klingler, S., Greser, J., Sebastian, T., Leven, B., Lösch, J., Hillebrands, B.: Annealing influence on the Gilbert damping parameter and the exchange constant of CoFeB thin films. Appl. Phys. Lett. 104, 182407 (2014). https://doi.org/10.1063/1.4875927
Xu, F., Phuoc, N.N., Zhang, X., Ma, Y., Chen, X., Ong, C.K.: Tuning of the magnetization dynamics in as-sputtered FeCoSiN thin films by various sputtering gas pressures. J. Appl. Phys. 104, 093903 (2008). https://doi.org/10.1063/1.3006006
Xu, F., Huang, Q., Liao, Z., Li, S., Ong, C.K.: Tuning of magnetization dynamics in sputtered CoFeB thin film by gas pressure. J. Appl. Phys. 111, 07A304 (2012). https://doi.org/10.1063/1.3670605
Jhajhria, D., Pandya, D.K., Chaudhary, S.: Interplay of composition and anisotropy on evolution of microstructural, static and dynamic magnetic properties of CoFeB thin films on annealing. J. Alloys Compd. 763, 728–735 (2018). https://doi.org/10.1016/j.jallcom.2018.05.322
Liu, X., Zhang, W., Carter, M.J., Xiao, G.: Ferromagnetic resonance and damping properties of CoFeB thin films as free layers in MgO-based magnetic tunnel junctions. J. Appl. Phys. 110, 033910 (2011). https://doi.org/10.1063/1.3615961
Hayakawa, J., Ikeda, S., Lee, Y.M., Sasaki, R., Meguro, T., Matsukura, F., Takahashi, H., Ohno, H.: Current-driven magnetization switching in CoFeB/MgO/CoFeB magnetic tunnel junctions. Jpn. J. Appl. Phys. 44, L1267–L1270 (2005). https://doi.org/10.1143/JJAP.44.L1267
Parkin, S.S.P., Kaiser, C., Panchula, A., Rice, P.M., Hughes, B., Samant, M., Yang, S.-H.: Giant tunnelling magnetoresistance at room temperature with MgO (100) tunnel barriers. Nat. Mater. 3, 862–867 (2004). https://doi.org/10.1038/nmat1256
Park, C., Zhu, J.-G., Moneck, M.T., Peng, Y., Laughlin, D.E.: Annealing effects on structural and transport properties of rf-sputtered CoFeB∕MgO∕CoFeB magnetic tunnel junctions. J. Appl. Phys. 99, 08A901 (2006). https://doi.org/10.1063/1.2165141
O’Dell, R.A., Phillips, A.B., Georgiev, D.G., Jones, J.G., Brown, G.J., Heben, M.J.: Post-deposition annealing effects on ferromagnetic CoFeB thin films. IEEE Trans. Magn. 54, 1–7 (2018). https://doi.org/10.1109/TMAG.2018.2845394
Cho, J., Jung, J., Cho, S.-Y., You, C.-Y.: Effect of annealing temperature on exchange stiffness of CoFeB thin films. J. Magn. Magn. Mater. 395, 18–22 (2015). https://doi.org/10.1016/j.jmmm.2015.06.073
Arteaga-Duran, A., Saenz-Hernandez, R., Santillan-Rodriguez, C., Botello-Zubiate, M., Grijalva-Castillo, M., Matutes-Aquino, J.: Effects of thickness and thermal annealing of FeCoB thin films on ferromagnetic resonance and microwave propagation properties. IEEE Trans. Magn. 55, 1–3 (2019). https://doi.org/10.1109/TMAG.2018.2872126
Harres, A., Mallmann, T.A., Gamino, M., Correa, M.A., Viegas, A.D.C., da Silva, R.B.: Magnetization reversal processes in amorphous CoFeB thin films. J. Magn. Magn. Mater. 552, 169135 (2022). https://doi.org/10.1016/j.jmmm.2022.169135
Dwivedi, J., Gupta, M., Reddy, V.R., Mishra, A., Pandit, P., Gupta, A.: Anomalous behavior of magnetic anisotropy of amorphous Co 40 Fe 43 B 17 thin film sandwiched between Mo layers. IEEE Trans. Magn. 57, 1–5 (2021). https://doi.org/10.1109/TMAG.2020.3012600
Barwal, V., Husain, S., Behera, N., Goyat, E., Chaudhary, S.: Growth dependent magnetization reversal in Co 2 MnAl full Heusler alloy thin films. J. Appl. Phys. 123, 053901 (2018). https://doi.org/10.1063/1.5004425
Stoner, E.C., Wohlfarth, E.P.: A mechanism of magnetic hysteresis in heterogeneous alloys. Philos. Trans. R. Soc. London. Ser. A, Math. Phys. Sci. 240, 599–642 (1948). https://doi.org/10.1098/rsta.1948.0007
Methfessel, S., Middelhoek, S., Thomas, H.: Partial rotation in permalloy films. J. Appl. Phys. 32, 1959–1963 (1961). https://doi.org/10.1063/1.1728270
McCord, J., Schäfer, R., Mattheis, R., Barholz, K.-U.: Kerr observations of asymmetric magnetization reversal processes in CoFe/IrMn bilayer systems. J. Appl. Phys. 93, 5491–5497 (2003). https://doi.org/10.1063/1.1562732
Smith, D.O., Cohen, M.S., Weiss, G.P.: Oblique-incidence anisotropy in evaporated permalloy films. J. Appl. Phys. 31, 1755–1762 (1960). https://doi.org/10.1063/1.1735441
Chowdhury, N., Mallick, S., Mallik, S., Bedanta, S.: Study of magnetization relaxation in Co thin films prepared by substrate rotation. Thin. Solid Films. 616, 328–334 (2016). https://doi.org/10.1016/j.tsf.2016.08.043
Chowdhury, N., Bedanta, S.: Controlling the anisotropy and domain structure with oblique deposition and substrate rotation. AIP Adv. 4, 027104 (2014). https://doi.org/10.1063/1.4865248
Garcia, D., Munoz, J.L., Kurlyandskaya, G., Vazquez, M., Ali, M., Gibbs, M.R.J.: Magnetic domains and transverse induced anisotropy in magnetically soft CoFeB amorphous thin films. IEEE Trans. Magn. 34, 1153–1155 (1998). https://doi.org/10.1109/20.706424
Idigoras, O., Suszka, A.K., Vavassori, P., Landeros, P., Porro, J.M., Berger, A.: Collapse of hard-axis behavior in uniaxial Co films. Phys. Rev. B. 84, 132403 (2011). https://doi.org/10.1103/PhysRevB.84.132403
Alben, R., Becker, J.J., Chi, M.C.: Random anisotropy in amorphous ferromagnets. J. Appl. Phys. 49, 1653–1658 (1978). https://doi.org/10.1063/1.324881
Diaz, J., Hamdan, N., Jalil, P., Hussain, Z., Valvidares, S.M., Alameda, J.M.: Understanding the magnetic anisotropy in Fe-Si amorphous alloys. IEEE Trans. Magn. 38, 2811–2813 (2002). https://doi.org/10.1109/TMAG.2002.803566
Kipgen, L., Fulara, H., Raju, M., Chaudhary, S.: In-plane magnetic anisotropy and coercive field dependence upon thickness of CoFeB. J. Magn. Magn. Mater. 324, 3118–3121 (2012). https://doi.org/10.1016/j.jmmm.2012.05.012
Woltersdorf, G.: Spin-pumping and two-magnon scattering in magnetic multilayers, (2001)
Mankovsky, S., Ködderitzsch, D., Woltersdorf, G., Ebert, H.: First-principles calculation of the Gilbert damping parameter via the linear response formalism with application to magnetic transition metals and alloys. Phys. Rev. B. 87, 014430 (2013). https://doi.org/10.1103/PhysRevB.87.014430
Kim, J.-S., Kim, G., Jung, J., Jung, K., Cho, J., Kim, W.-Y., You, C.-Y.: Control of crystallization and magnetic properties of CoFeB by boron concentration. Sci. Rep. 12, 4549 (2022). https://doi.org/10.1038/s41598-022-08407-6
Gupta, A., Bhagat, N., Principi, G., Hernando, A.: Formation of nanocrystalline phases by crystallization of metallic glasses. J. Magn. Magn. Mater. 133, 291–294 (1994). https://doi.org/10.1016/0304-8853(94)90549-5
Hofmann, B., Kronmüller, H.: Stress-induced magnetic anisotropy in nanocrystalline FeCuNbSiB alloy. J. Magn. Magn. Mater. 152, 91–98 (1996). https://doi.org/10.1016/0304-8853(95)00447-5
Suzuki, Y., Haimovich, J., Egami, T.: Bond-orientational anisotropy in metallic glasses observed by x-ray diffraction. Phys. Rev. B. 35, 2162–2168 (1987). https://doi.org/10.1103/PhysRevB.35.2162
Hindmarch, A.T., Rushforth, A.W., Campion, R.P., Marrows, C.H., Gallagher, B.L.: Origin of in-plane uniaxial magnetic anisotropy in CoFeB amorphous ferromagnetic thin films. Phys. Rev. B. 83, 212404 (2011). https://doi.org/10.1103/PhysRevB.83.212404
West, F.G.: Uniaxial anisotropy due to magnetoelastic energy in constrained polycrystalline films. J. Appl. Phys. 35, 1827–1840 (1964). https://doi.org/10.1063/1.1713750
Wang, Y., Wei, D., Gao, K.-Z., Cao, J., Wei, F.: The role of inhomogeneity of perpendicular anisotropy in magnetic properties of ultra thin CoFeB film. J. Appl. Phys. 115, 053901 (2014). https://doi.org/10.1063/1.4863139
Acknowledgements
CM would like to acknowledge funding from the SERB-Early Career Research Award (ECR/2018/002664) and the Board of Research in Nuclear Sciences, India (58/14/04/2022-BRNS). AH would like to acknowledge funding from the Board of Research in Nuclear Sciences, India (DAE-YSRA 59/20/05/2021-BRNS). KS would like to acknowledge the fellowship from the SERB project (ECR/2018/002664). BP would like to acknowledge a fellowship from the Department of Science and Technology, India (DST/INSPIRE Fellowship/ [IF180927]). The authors would like to thank Miss. Savita Sahu for helping in measurements.
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Sriram, K., Pala, J., Mondal, R. et al. Effect of Annealing on Magnetization Reversal and Spin Dynamics in Co40Fe40B20 Thin Films. J Supercond Nov Magn 36, 155–162 (2023). https://doi.org/10.1007/s10948-022-06442-y
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DOI: https://doi.org/10.1007/s10948-022-06442-y