Abstract
We have studied the magnetic properties of transition metal intercalated niobium dichalcogenides CoNb\(_3\)S\(_6\), NiNb\(_3\)S\(_6\) and CuNb\(_3\)S\(_6\), which are synthesized by a chemical vapor transport (CVT) method using TeBr\(_4\) as transport agent in a horizontal two-zone tube furnace. CoNb\(_3\)S\(_6\) and NiNb\(_3\)S\(_6\) order antiferromagnetically below 30(2) K and 44(3) K, respectively. At high temperatures, the magnetic susceptibility is well described by the Curie-Weiss law and the deduced effective magnetic moments are 4.6(1) \(\mu\) \(_B\)/Co for CoNb\(_3\)S\(_6\) and 2.6(6) \(\mu\) \(_B\)/Ni for NiNb\(_3\)S\(_6\). In the case of CuNb\(_3\)S\(_6\), no magnetic phase transition is observed from 2 to 300 K.
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This project is supported by the Zhengzhou University of Light Industry Foundation of China (Grant No. 2012XJJ008) and the Key Project of Scientific and Technological Research of the Education Department of Henan Province (Grant No. 13B140332).
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Feng, X., Wu, J. Synthesis and Magnetic Properties of TNb\(_3\)S\(_6\) (T = Co, Ni, Cu). J Supercond Nov Magn 35, 3347–3351 (2022). https://doi.org/10.1007/s10948-022-06358-7
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DOI: https://doi.org/10.1007/s10948-022-06358-7