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Magnetic, Magnetocaloric Properties and Phenomenological Model of Perovskite Type: Sr3Fe2+xMo1−xO9−3x/2 (x = 0.45, 0.60, and 1.00)

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Abstract

We investigate in detail the magnetic, magnetocaloric properties and phenomenological model of perovskite type: Sr3Fe2+xMo1−xO9−3x/2(x = 0.45, 0.60, and 1.00). The solid-state reaction route in the air was used to synthesize the three polycrystalline compounds. With a Curie temperature from 132 to 144 K, the magnetic transition nature undergoes a second-order magnetic phase transition from ferromagnetic to paramagnetic states. We have used the thermodynamic Maxwell relation to determine the magnetic entropy change (− ∆SM) in the studied structures. Moreover, we report a theoretical investigation of the magnetocaloric effect using a phenomenological model. The model parameters and their variation with temperature and the magnetic field were obtained. The theoretical predictions (adopted model) were found to be consistent with the experimental results.

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Authors and Affiliations

  1. Laboratoire Rayonnement-Matière Et Instrumentation, Université Hassan 1, S3M, FST, Settat, Morocco

    A. El Hachmi & B. Manoun

  2. Faculté Des Sciences Ain Chock, LPMAT, Université Hassan II de Casablanca, BP 5366, Mâarif, Casablanca, Morocco

    S. El Ouahbi & H. Lassri

  3. Materials Science and Nano Engineering (MSN), University Mohammed VI Polytechnic, Ben Guerir, Morocco

    B. Manoun

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  1. A. El Hachmi
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  2. S. El Ouahbi
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  3. B. Manoun
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  4. H. Lassri
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Correspondence to S. El Ouahbi.

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Hachmi, A.E., Ouahbi, S.E., Manoun, B. et al. Magnetic, Magnetocaloric Properties and Phenomenological Model of Perovskite Type: Sr3Fe2+xMo1−xO9−3x/2 (x = 0.45, 0.60, and 1.00). J Supercond Nov Magn 35, 1299–1306 (2022). https://doi.org/10.1007/s10948-022-06170-3

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  • DOI: https://doi.org/10.1007/s10948-022-06170-3

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