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Neutron Diffraction Magnetic and Mossbauer Spectroscopic Studies of Pb0.8Bi0.2Fe0.728W0.264O3 and Pb0.7Bi0.3Fe0.762W0.231O3 Ceramics

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Abstract

We report on high-temperature crystallographic structure, magnetic and physical properties of chemically B-site disordered lead-bismuth iron tungstate, (PFW)1−x(BFO)x (which can be written as Pb0.8Bi0.2Fe0.728W0.264O3 (0.8PFW–0.2BFO) for x = 0.2 and Pb0.7Bi0.3Fe0.762W0.231O3 (0.7PFW–0.3BFO) for x = 0.3) or PBFW), solid solutions through neutron diffraction (ND), magnetization, electron paramagnetic resonance, and Mössbauer spectroscopic studies. From the high temperature magnetic susceptibility measurement, it is observed that increase antiferromagnetic to paramagnetic phase transition around TN = 435 K (Pb0.8Bi0.2Fe0.728W0.264O3) and 504 K (Pb0.7Bi0.3Fe0.762W0.231O3), compared to pure PFW. Room-temperature crystallographic study confirms the formation of pseudo cubic structure with Pm-3m space group, whereas the magnetic structure is commensurate G-type antiferromagnetic ordering. The obtained temperature dependent structural parameters from the ND, evidenced to existence of strong spin-lattice coupling around TN for both the compounds. The discontinuity in the Pb/Bi–O bond length around ferroelectric transition (TC) indicates the presence of magnetoelectric coupling. Interestingly, microscopic 1:1 B-site ordered nanoclusters of PBFW exhibits the ferrimagnetic clusters along with antiferromagnetic order and it observed through the opening of M vs H hysteresis curves in the lower field regime. The EPR and Mössbauer spectroscopic studies well support the magnetic property and also reveal the Fe+3 state, and the weak signal in EPR and broader linewidth in the Mössbauer spectra exhibit the B-site disorderliness.

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Acknowledgments

The authors (SI, SM, and BA) thank UGC-DAE-CSR, Mumbai Centre, for the financial support and experimental facilities through the CRS-M-200 project. The author (SI) thanks the Council of Scientific and Industrial Research (CSIR), New Delhi, for the SRF award. The author (SM) thanks the Vision Group on Science and Technology (VGST) Government of Karnataka for sanctioning the project in “Center for Excellence in Science Engineering and Medicine.” Also, the authors thank the DST–FIST and UGC-CPEPA program for providing XRD and Raman facilities, respectively, at the Department of Physics, Bangalore University, Bengaluru. Dr. SP Kubrin acknowledges the financial support from the Ministry of Science and Higher Education of the Russian Federation (State assignment in the field of scientific activity, Southern Federal University, 2020).

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Authors and Affiliations

  1. Department of Physics, Bangalore University, Jnanabharathi Campus, Bangalore, 560 056, India

    I. Shivaraja & Basavaraj Angadi

  2. Department of Physics, Basavaprabhu Kore, Arts Science and Commerce College, Chikodi, 59120, India

    Shidaling Matteppanavar

  3. Solid State Physics Division, BARC, Mumbai, 400085, India

    P. S. R. Krishna

  4. UGC-DAE-Consortium for Scientific Research, Mumbai Centre, BARC Campus, Mumbai, 400085, India

    Sudhindra Rayaprol & P. D. Babu

  5. Deparment of Physics, P.C. Jabin Science College, Hubballi, 31, India

    V. Jagadeesha Angadi

  6. Research institute of physics, Southern Federal University, Stachkiav.194, Rostov-on-Don, Russia, 344090

    S. P. Kubrin

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Shivaraja, I., Matteppanavar, S., Krishna, P.S.R. et al. Neutron Diffraction Magnetic and Mossbauer Spectroscopic Studies of Pb0.8Bi0.2Fe0.728W0.264O3 and Pb0.7Bi0.3Fe0.762W0.231O3 Ceramics. J Supercond Nov Magn 34, 925–941 (2021). https://doi.org/10.1007/s10948-021-05805-1

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