Abstract
The (FeCo)1−xCux (X = 0.1–0.5) nanowire (NWs) arrays were synthesized through AC-electrochemical deposition in anodized aluminum oxide (AAO) templates. The morphology and composition of the synthesized (FeCoCu) NWs were found from scanning electron microscope (SEM), and energy dispersive X-ray spectroscopy (EDS) that confirmed the diameter of the NWs is in the range of 50–60 nm and the composition of FeCoCu alloy NWs, respectively. The XRD measurement of the NWs was carried out in AAO templates along with Al-substrate. The FeCoCu alloy NWs show BCC phase along with reflection peak (311) in all samples which corresponds to Al-substrate. The crystallite size displays overall increasing trend confirmed through XRD using Scherrer equation. The magnetic analysis reveals that by increasing the Cu concentration in FeCoCu alloy NWs, the saturation magnetization and coercivity (Hc) decreased. The results of MH loops confirmed that easy axis lies along the NWs and hard axis perpendicular to the NWs due to dominance of shape anisotropy. Magnetization reversal mechanism occurs by nucleation mode with the motion of domain walls. The frequency-dependent dielectric analysis investigated thoroughly using impedance and the behavior of dielectric parameters has been examined using Maxwell-Wagner’s model and Koop’s theory. The value of dielectric constant decreases progressively with increasing frequency and vice versa. It is also observed that with increase in Cu concentration, the dielectric constant also decreases due to higher conductivity of Cu than Fe and Co.
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Al-Mawlawi, D., Liu, C.Z., Moskovits, M.: Nanowires formed in anodic oxide nanotemplates. J. Mater. Res. 04, 1014–1018 (1994)
Wäckelgård, E.: A study of the optical properties of nickel-pigmented anodic alumina in the infrared region. J. Phys. Condens. Matter. 8, 5125 (1996)
Fodor, P.S., Tsoi, G.M., Wenger, L.E.: Fabrication and characterization of Co1− xFe x alloy nanowires. J. Appl. Phys. 10, 8186–8188 (2002)
Avella, M., Cocca, M., Errico, M.E., Gentile, G.: Nanotechnologies and nanosensors: future applications for the conservation of cultural heritage. Nanotechnol. Basis Adv. Sensors. 3, 511–517 (2011)
Ramazani, A., Almasi-Kashi, M., Golafshan, E., Arefpour, M.: Magnetic behavior of as-deposited and annealed CoFe and CoFeCu nanowire arrays by ac-pulse electrodeposition. J. Cryst. Growth. 402, 42–47 (2014)
Darques, M., De la Torre Medina, J., Piraux, L., Cagnon, L., Huynen, I.: Microwave circulator based on ferromagnetic nanowires in an alumina template. Nanotechnology. 14, 145208 (2010)
Saavedra, E., Saez, G., Díaz, P., Cisternas, E., Vogel, E.E., Escrig, J.: Dynamic susceptibility of modulated magnetic nanowires. AIP Adv. 9, 065007 (2019)
Berganza, E., Bran, C., Jaafar, M., Vázquez, M., Asenjo, A.: Domain wall pinning in FeCoCu bamboo-like nanowires. Sci. Rep. 6, 29702 (2017)
Fodor, P.S., Tsoi, G.M., Wenger, L.E.: Fabrication and characterization of Co1− xFex alloy nanowires. J. Appl. Phys. 10, 8186–8188 (2002)
Wang, R.L., Tang, S.L., Shi, Y.G., Fei, X.L., Nie, B., Du, Y.W.: Effects of annealing on the structure and magnetic properties of Fe27Co23Pb50 nanowire arrays. J. Appl. Phys. 103, 07D507 (2008)
Shukla, G.: Magnetic and optical properties of epitaxial n-type Cu-doped ZnO thin films deposited on sapphire substrates. Appl. Phys. A Mater. Sci. Process.1(115–118), (2009)
Guo, Y., Qin, D.-H., Ding, J.-B., Li, H.-L.: Annealing and morphology effects on the Fe 0.39 Co 0.61 nanowire arrays. Appl. Surf. Sci.218, 107–113 (2003)
Khan, S., Ahmad, N., Ahmed, N., Safeer, A., Iqbal, J., Han, X.F.: Structural, magnetic and transport properties of Fe-based full Heusler alloy Fe2CoSn nanowires prepared by template-based electrodeposition. J. Magn. Magn. Mater. 465, 462–470 (2018)
Khan, S., Ahmad, N., Safeer, A., Iqbal, J.: Compositional dependent morphology, structural and magnetic properties of Fe100─XCuX alloy nanowires via electrodeposition in AAO templates. Appl. Phys. A. 678, 124 (2018)
Laocharoensuk, R., Bulbarello, A., Mannino, S., Wang, J.: Adaptive nanowire–nanotube bioelectronic system for on-demand bioelectrocatalytic transformations. Chem. Commun. 32, 3362–3364 (2007)
Palmero, E.M., Bran, C., Rafael, P., Magén, C., Vázquez, M.: Structural and magnetic characterization of FeCoCu/Cu multilayer nanowire arrays. IEEE Magn. Lett.5, 1–4 (2014)
Ahmad, N., Chen, J.Y., Iqbal, J., Wang, W.X., Zhou, W.P., Han, X.F.: Temperature dependent magnetic properties of Co nanowires and nanotubes prepared by electrodeposition method. J. Appl. Phys.109, 07A331 (2011)
Méndez, M., González, S., Vega, V., Teixeira, J.M., Hernando, B., Luna, C., Prida, V.M.: Ni-Co alloy and multisegmented Ni/Co nanowire arrays modulated in composition: structural characterization and magnetic properties. Crystals. 7, 66 (2017)
Bran, C., Ivanov, Y.P., García, J., Del Real, R.P., Prida, V.M., Chubykalo-Fesenko, O., Vázquez, M.: Tuning the magnetization reversal process of FeCoCu nanowire arrays by thermal annealing. J. Appl. Phys.114, 043908 (2013)
Han, G.C., Zong, B.Y., Luo, P.: Angular dependence of the coercivity and remanence of ferromagnetic nanowire arrays. J. Appl. Phys. 93, 11 (2003)
Kumar, G., et al.: Electric and dielectric study of cobalt substituted Mg-Mn nanoferrites synthesized by solution combustion technique. Ceram. Int. 39(5), 4813–4818 (2013)
Mazen, S., Mansour, S., Zaki, H.: Some physical and magnetic properties of Mg-Zn ferrite. Cryst. Res. Technol. 38(6), 471–478 (2003)
Kharabe, R., et al.: Dielectric properties of mixed Li–Ni–Cd ferrites. Smart Mater. Struct. 15(2), N36 (2006)
Mazen, S., Zaki, H.: Effect of tetra ionic substitution on the dielectric properties of Cu-ferrite. Phys. Status Solidi A. 199(2), 305–320 (2003)
Mazen, S.: Infrared absorption and dielectric properties of Li–Cu ferrite. Mater. Chem. Phys. 62(2), 139–147 (2000)
Núñez, A., Pérez, L., Abuín, M., Araujo, J.P., Proenca, M.P.: Magnetic behaviour of multisegmented FeCoCu/Cu electrodeposited nanowires. Phys. D Appl. Phys. 50, 155003 (2017)
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This project is supported by Higher Education Commission, Pakistan, by Pakistan through Pakistan Programme for Collaborative Research (PPCR).
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Ahmad, N., Shafiq, M.Z., Khan, S. et al. Dominance of Shape Anisotropy among Magnetostatic Interaction and Magnetocrystalline Anisotropy in Electrodeposited (FeCo)1−xCux (X = 0.1–0.5) Ternary Alloy Nanowires. J Supercond Nov Magn 33, 1495–1505 (2020). https://doi.org/10.1007/s10948-019-05394-0
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DOI: https://doi.org/10.1007/s10948-019-05394-0