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Effect of Heat Treatment on Microstructure and Magnetic Properties of Ce-Doped NdFeB Ribbons

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Abstract

The substitution for Nd by abundant element cerium (Ce) is a practical way for the comprehensive utilization of rare earth resources in NdFeB permanent magnets. In this letter, we have prepared the Ce-doped NdFeB ribbons and conventional NdFeB ribbons by melt quenching method and investigated the effects of heat treatment on the crystallization behavior, microstructure, and magnetic properties of the alloy. The results show that: (1) The crystallization behavior and the microstructural changes of the (Nd,Ce)FeB magnets are similar to the conventional NdFeB magnet when heat treatment. In addition, the Ce2Fe14B phase has a significant effect on the properties of the whole magnets. (2)The NdFeB phase and CeFeB phase are relatively close to each other after being precipitated from the amorphous phase. The coupling effect between the two phases is strong enough to weaken the effect of the addition of Ce and making the properties of the NdFeB magnets to not reduce too much after adding Ce.

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References

  1. Hu, B.P.: Status and development tendency of rare-earth permanent magnet materials. J. Magn. Mater. Devices 7(2), 66–77 (2014)

    Google Scholar 

  2. Zhang, M.G., Li, L., Chen, F.H., Li, M.J.: Magnetic properties of multilayer and alternative multilayer NdFeB/Nd thin films. Rare Met. Mater. Eng. 01, 270–273 (2017)

    Google Scholar 

  3. Stuhlpfarrer, P., Luidold, S., Antrekowitsch, H.: Recycling of Nd2Fe14B magnets. World of Metallurgy-ERZMETALL 68(5), 278–285 (2015)

    Google Scholar 

  4. Zhu, M.G., Li, W.: Status and prospect for multi-(hard magnetic) main-phase permanent magnet and coercivity mechanism. Chin. Sci. Bull. 60, 3161–3168 (2015)

    Google Scholar 

  5. Zhang, X., Shi, Y., Ma, Q.: Magnetic properties and microstructure of Re-Fe-B permanent magnet prepared using mixed rare earth of Bayan Obo. Rare Met. Mater. Eng. 44(3343), 232–236 (2015)

    Google Scholar 

  6. Zhou, Q.Y., Liu, Z., Guo, S.: Magnetic properties and microstructure of melt-spun Ce–Fe–B magnets. IEEE Trans. Magn. 51(11), 1–4 (2015)

    Google Scholar 

  7. Zhang, X.F., Shi, M.F., Li, P.-Z.: Effect of Ce addition on magnetic properties and microstructure of NdFeB based rare earth permanent magnets. Chin. Rare Earths 34(4), 12–16 (2013)

    ADS  Google Scholar 

  8. Herbst, J.F., Meyer, M.S., Pinkerton, F.E.: Magnetic hardening of Ce2Fe14B. J. Appl. Phys. 111(7), 819 (2012)

    Article  Google Scholar 

  9. Li, Z.B., Shen, B.G., Zhang, M.: Substitution of Ce for Nd in preparing R2Fe14B nanocrystalline magnets. J. Alloys Compd. 628, 325–328 (2015)

    Article  Google Scholar 

  10. Yan, C.-J., Guo, S., Chen, R.-J.: Phase constitution and microstructure of Ce-Fe-B strip-casting alloy. Chin. Phys. B 23(10), 508–512 (2014)

    Google Scholar 

  11. Pathak, A.K., Khan, M., Gschneidner Jr, K.A.: Magnetic properties of bulk, and rapidly solidified nanostructured (Nd1−xCex)2Fe14−yCoyB ribbons. Acta Mater. 103, 211–216 (2016)

    Article  Google Scholar 

  12. Wang, X., Zhu, M.G., Li, W.: Effects of the ingot phase transition on microstructure and magnetic properties of CeNdFeB melt-spun ribbons. Phys. B Condens. Matter 476, 150–153 (2015)

    Article  ADS  Google Scholar 

  13. Mayot, H., Isnard, O., Soubeyroux, J.L.: Magnetic properties and synthesis conditions of Nd2Fe23B3, melt-spun alloy. J. Magn. Magn. Mater. 316(2), e477—e480 (2007)

    Article  Google Scholar 

  14. Jung, Y.C., Nakai, K.: Effects of Cr on the early crystallization stages of Nd4.5Fe77−xCrxB18.5, amorphous ribbons. Met. Mater. Int. 9(4), 337–344 (2003)

    Article  Google Scholar 

  15. Huang, S.L., Feng, H.B.: Optimal design of sintered Ce9Nd21Fe bal b 1 magnets with a low-melting-point (Ce, Nd)-rich phase. Int. J. Miner. Metall. Mater. 4, 417–422 (2015)

    Article  Google Scholar 

  16. Ćosović, V., Grujić, A., Stajićtrošić, J., et al.: Phase composition and magnetic properties of multiphase melt-spun Nd4.3Fe76.2B19.5 alloy. Research Trends in Contemporary Materials Science (2007)

  17. Susner, M.A., Conner, B.S., Saparov, B.I., et al.: Growth and characterization of Ce-substituted Nd2Fe14B single crystals. Physics (2016)

  18. Zhang, X.S., Zhang, M.G., Li, H.: Developments of NdFeB-type nanocomposite dualphase rare-earth permanent magnetic material. Elect. Components Mater. 02, 71–75 (2011)

    Google Scholar 

  19. Hirosawa, S., Matsuura, Y., Yamamoto, H., et al.: Magnetization and magnetic anisotropy of R2Fe14B measured on single crystals. J. Appl. Phys. 59(3), 873–879 (1986)

    Article  ADS  Google Scholar 

  20. Boltich, E.B., swald, E.O., Huang, M.Q., et al.: Magnetic characteristics of R2Fe14B systems prepared with high purity rare earths (R=Ce, Pr, Dy, and Er). J. Appl. Phys. 57(8), 4106–4108 (1985)

    Article  ADS  Google Scholar 

  21. Huang, S., Feng, H., Zhu, M., et al.: Investigation of chemical composition and crystal structure in sintered Ce15Nd15FebalB magnet. AIP Advances 4(10), 4106 (2014)

    Google Scholar 

  22. Capehart, T.W., Mishra, R.K.: Steric variation of the cerium valence in Ce2Fe14B and related compounds. Appl. Phys. Lett. 65(24), 3149–3150 (1994)

    Article  ADS  Google Scholar 

  23. Chaboy, J., Garcia, J.: Comment on Steric variation of the cerium valence in Ce2Fe14B and related. Applied Physics Letters (1994)

  24. Alam, A., Khan, M., Mccallum, R.W., et al.: Site-preference and valency for rare-earth sites in (R-Ce)2Fe14B magnets. Appl. Phys. Lett. 102(4), 4176 (2013)

    Article  Google Scholar 

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Funding

This work is supported by Shanxi Science and Technology Foundation Platform Construction Projects (2015091011), Jincheng Science and Technology Planning Projects (201501004-21), Taiyuan Science and Technology Planning Projects (110153), China Postdoctoral Science Foundation-funded project (2015M571285), the Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Province, Research Project supported by Shanxi Scholarship Council of China (2013-098, 2016-092), and Proposal of Open Project of Key Laboratory for Anisotropy and Texture of Materials, Ministry of Education Northeastern University (ATM20170003).

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Correspondence to Mingang Zhang.

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Zhang, M., Zhang, W., Chen, F. et al. Effect of Heat Treatment on Microstructure and Magnetic Properties of Ce-Doped NdFeB Ribbons. J Supercond Nov Magn 31, 2811–2816 (2018). https://doi.org/10.1007/s10948-017-4553-z

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  • DOI: https://doi.org/10.1007/s10948-017-4553-z

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