Abstract
The Fe vacancy and its ordering pattern is a unique property of the A x Fe2−y Se2 (A = K, Rb, Cs) superconductors. Below the structural transition temperature T S ∼ 550 K, the system phase separates into the I4/mmm phase with no Fe vacancy and the I4/m phase with the \(\sqrt 5\times \sqrt 5\times 1\) vacancy order. In this work, an Ising-like Hamiltonian defined on the Fe-sublattice is constructed and employed in a Metropolis Monte Carlo simulation to study the Fe vacancy order and the domain distribution under different thermal treatments. A third phase with randomly distributed Fe vacancies and space group I4/mmm is observed in the simulation. The response of the volume fraction of this simulated phase under thermal treatment shows a direct connection to the change of the superconducting shielding fraction under annealing and quenching processes, indicating a close relation between the vacancy disordered I4/mmm phase and the superconducting phase.
Similar content being viewed by others
References
Guo, J., et al.: Phys. Rev. B 82, 180520(R) (2010)
Ricci, A., et al.: Supercond. Sci. Technol. 24, 082002 (2011)
Ricci, A., et al.: Phys. Rev. B 84, 060511(R) (2011)
Li, W., et al.: Nat. Phys. 8, 126–130 (2012)
Yuan, R., et al.: Sci. Rep. 2, 221 (2012)
Bao, W., et al.: Chin. Phys. Lett. 28, 086104 (2011)
Bao, W., et al.: Chin. Phys. Lett. 30, 027402 (2013)
Ye, F., et al.: Phys. Rev. Lett. 107, 137003 (2011)
Zavalij, P., et al.: Phys. Rev. B. 83, 132509 (2011)
Wang, Z., et al.: Phys. Rev. B. 83, 140505(R) (2011)
Yan, Y., et al.: Sci. Rep. 2, 212 (2012)
Kazakov, S., et al.: Chem. Mater. 23, 4311 (2011)
Ding, X., et al.: Nat. Commun. 4, 1897 (2013)
Duan, C., et al.: arXiv:1706.02182v2 (2017)
Bendele, M., et al.: Sci. Rep. 4, 5592 (2014)
Han, F., et al.: Philos. Mag. 92, 2553 (2012)
Ryu, H., et al.: Phys. Rev. B 85, 224515 (2012)
Yang, J., et al.: Phys. Rev. B 94, 024503 (2016)
Berlijn, T., et al.: Phys. Rev. Lett. 109, 147003 (2012)
Acknowledgements
The work at the University of Virginia is supported by the U.S. Department of Energy, Office of Basic Energy Science, DE-FG02-01ER45927.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Duan, C., Louca, D. Fe Vacancy Order and Domain Distribution in A x Fe2−y Se2 . J Supercond Nov Magn 31, 757–761 (2018). https://doi.org/10.1007/s10948-017-4381-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10948-017-4381-1