Abstract
FePt thin films were prepared by pulsed laser deposition (PLD) on SiO2/Si (100) and Si (100) singlecrystal substrates at different temperatures of 600, 700 and 800∘C. In all samples, the external magnetic field produced by a permanent magnet has been used to improve and control the intensity of the laser plume. X-ray diffraction analysis showed that the L1 crystal structure was created and the long-range order parameter increased from near 0.6 to a maximum of 0.98 in films grown at 800∘C for two types of films. The increasing of stress in FePt/Si (100) thin films due to the lattice mismatch leads to the change of surface morphology from the island-like mode with grain separation to interconnected grains that have a tendency to grow in a specific direction. Moreover, the roughness of the surface increased by increasing the lattice mismatch and temperature. In addition, the maximum value (over 9400 Oe) of coercivity was obtained by increasing the temperature to 800∘C using SiO2/Si (100) substrate. All series of films grown on SiO2/Si (100) show a large K u of 10.2×107 erg/cm3at the temperature of 800∘C.
This is a preview of subscription content, access via your institution.










References
- 1.
Weller, D., Moser, A., Folks, L., Best, M.E., Lee, W., Toney, M.F., Schwickert, M., Thiele, J.U., Doerner, M.F.: High Ku materials approach to 100 Gbits/in2. IEEE Trans. Magn. 36(1), 10–15 (2000)
- 2.
Seki, T.O., Takahashi, Y.K., Hono, K.: Microstructure and magnetic properties of FePt-SiO2 granular films with Ag addition. J. Appl. Phys. 103(2), 23910–23910 (2008)
- 3.
Richter, H.J., Harkness, S.D.: Media for magnetic recording beyond 100Gbit/in2. MRS Bulletin 31(05), 384–388 (2006)
- 4.
Sun, S., Murray, C.B., Weller, D., Folks, L., Moser, A.: Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices. Science 287(5460), 1989–1992 (2000)
- 5.
Piramanayagam, S.N.: Perpendicular recording media for hard disk drives. J. Appl. Phys. 102(1), 011301 (2007)
- 6.
Moser, A., Takano, K., Margulies, D.T., Albrecht, M., Sonobe, Y., Ikeda, Y., Sun, S., Fullerton, E.E.: Magnetic recording: advancing into the future. J. Phys. D. Appl. Phys. 35(19), R157 (2002)
- 7.
Zhang, L., Xue, S.X., Li, Z.G., Liu, Y.P., Chen, W.P.: FePt-C Granular thin film for heat-assisted magnetic recording (HAMR) media. Applied Physics A: Materials Science and Processing 116(3), 1257–1260 (2014)
- 8.
Seki, T., Shima, T., Takanashi, K., Takahashi, Y., Matsubara, E., Hono, K.: Optimum Compositions for the low-temperature fabrication of highly ordered FePt [001] and FePt [110] films. IEEE Trans. Magn. 40(4), 2522–2524 (2004)
- 9.
Chen, S.C., Chen, C.D., Sun, T.H., Ou, S.L., Shen, C.L, Su, W.H.: Effect of Pt Content on structure and magnetic properties of Fe100−xPtx films deposited on thermally oxidized Si substrates by rapid thermal annealing. Vacuum 87, 205–208 (2013)
- 10.
Yang, E., Laughlin, D.E.: L10 FePt-oxide columnar perpendicular media with high coercivity and small grain size. J. Appl. Phys. 104(2), 23904–23904 (2008)
- 11.
Varvaro, G., Laureti, S., Fiorani, D.: L10 FePt-based thin films for future perpendicular magnetic recording media. J. Magn. Magn. Mater. 368, 415–420 (2014)
- 12.
Speliotis, T., Varvaro, G., Testa, A.M., Giannopoulos, G., Agostinelli, E., Li, W., Hadjipanayis, G., Niarchos, D.: Microstructure and magnetic properties of (001) textured L10 FePt films on amorphous glass substrate. Appl. Surf. Sci. 337, 118–124 (2015)
- 13.
Kaushik, N., Sharma, P., Tanaka, S., Makino, A., Esashi, M.: Preferentially oriented growth of L10 FePt on Si substrate. Acta Physica Polonica A 127(2), 611–613 (2015)
- 14.
Richter, H.J.: The transition from longitudinal to perpendicular recording. J. Phys. D. Appl. Phys. 40(9), R149 (2007)
- 15.
Laughlin, D.E., Kumar, S., Peng, Y., Roy, A.G.: Engineering the microstructure of thin films for perpendicular recording. IEEE Trans. Magn. 41(2), 719–723 (2005)
- 16.
Lai, C.H., Chiang, C.C., Yang, C.H.: Low-temperature ordering of FePt by formation of silicides in underlayers. J. Appl. Phys. 97(10), 10H310-1–10H310-3 (2005)
- 17.
Thomson, T., Toney, M.F., Raoux, S., Baglin, J.E.E., Lee, S.L., Terris, B.D., Sun, S.: Silicide formation and particle size growth in high temperature annealed, self-assembled FePt nanoparticles (No SLAC-PUB-10213) (2003)
- 18.
Lim, B.C., Chen, J.S., Wang, J.P.: Thickness dependence of structural and magnetic properties of FePt films. J. Magn. Magn. Mater. 271(2), 431–436 (2004)
- 19.
Takahashi, Y.K., Ohnuma, M., Hono, K.: Ordering process of sputtered FePt films. J. Appl. Phys. 93 (10), 7580–7582 (2003)
- 20.
Gutfleisch, O., Lyubina, J., Müller, K.H., Schultz, L.: FePt hard magnets. Adv. Eng. Mater. 7(4), 208–212 (2005)
- 21.
Laughlin, D.E., Srinivasan, K., Tanase, M., Wang, L.: Crystallographic aspects of L10 magnetic materials. Scr. Mater. 53(4), 383–388 (2005)
- 22.
Zhang, A.M., Zhu, W.H., Zheng, L., Huang, L., Gao, J.L., Tang, S.L., Wu, X.S.: Magnetic anisotropy of L10-FePt film on (001) LaAlO3. J. Magn. Magn. Mater. 332, 89–92 (2013)
- 23.
Dong, K., Jin, F., Mo, W., Song, J., Cheng, W.: Investigation of microstructure and magnetic properties of FePtx films grown on MgO and STO substrates. J. Magn. Magn. Mater. 402, 124130 (2016)
- 24.
Dong, K., Jin, F., Mo, W., Song, J., Cheng, W.: Investigation of microstructure and magnetic properties of FePt films grown on different substrates. Mater. Lett. 164, 97103 (2016)
- 25.
Dong, K.F., Li, H.H., Chen, J.S.: Lattice mismatch-induced evolution of microstructural properties in FePt films. J. Appl. Phys. 113(23), 233904 (2013)
- 26.
Hotta, A., Ono, T., Hatayama, M., Tsumura, K., Kikuchi, N., Okamoto, S., Kitakami, O., Shimatsu, T.: Magnetic anisotropy and order structure of L10-FePt (001) single-crystal films grown epitaxially on (001) planes of MgO, SrTiO3, and MgAl2 O 4 substrates. Journal of Applied Physics 115(17), 17B712 (2014)
- 27.
Iwama, H., Doi, M., Shima, T.: Magnetization behavior of L10-ordered FePt alloy thin films prepared on MgO (100), MgAl2 O 4 (100), and KTaO3 (100) single-crystal substrates. Jpn. J. Appl. Phys. 55(7S3), 07MC03 (2016)
- 28.
Shen, C.L., Kuo, P.C., Lin, G.P., Chen, S.C., Huang, K.T.: Effect of film thickness on magnetic properties of FePt thin films deposited on amorphous substrate directly. IEEE Trans. Med. Imaging 47(10), 3889–3892 (2011)
- 29.
Wu, Y.C., Wang, L.W., Lai, C.H.: Low-temperature ordering of (001) granular FePt films by inserting ultrathin SiO2 layers. Appl. Phys. Lett. 91(7), 2502 (2007)
- 30.
Wang, Y.C., Ding, J., Yi, J.B., Liu, B.H., Yu, T., Shen, Z.X.: High-coercivity Co-ferrite thin films on (100)-SiO2 substrate. Appl. Phys. Lett. 84(14), 2596–2598 (2004)
- 31.
Trichy, G.R., Chakraborti, D., Narayan, J., Zhou, H.: Growth, characterization, and magnetic properties of FePt nanodots on Si (100). J. Appl. Phys. 102(3), 033901 (2007)
- 32.
Jang, P., Jung, C.S., Seomoon, K., Kim, K.H.: Interfacial structure of ferromagnetic Fe-Pt thin films grown on a Si substrate. Curr. Appl. Phys. 11(4), S95–S97 (2011)
- 33.
Maaß, R., Weisheit, M., Fähler, S., Schultz, L.: Influence of hydrogen on the growth of FePt thin films. J. Appl. Phys. 100(7), 073910 (2006)
- 34.
Mo, X., Xiang, H., Li, G., Chen, P., Xiong, Z., Wang, J., Ishio, S., Saito, H., Shima, T., Takanashi, K.: Magnetic properties of perpendicularly orientated L10 FePt nanoparticles. Chin. Sci. Bull. 55(8), 680–686 (2010)
- 35.
Rao, S.S., Prater, J.T., Wu, F., Nori, S., Kumar, D., Narayan, J.: Integration of epitaxial permalloy on Si (100) through domain matching epitaxy paradigm. Curr. Opinion Solid State Mater. Sci. 18(1), 1–5 (2014)
- 36.
Chen, S.C., Kuo, P.C., Lee, C.T., Sun, A.C., Chou, C.Y., Fang, Y.H.: Effects of CrRu underlayer and CrRu capped layer on the microstructure and magnetic properties of FePt films. IEEE Trans. Magn. 43(2), 876–878 (2007)
- 37.
Kim, H., Noh, J.S., Roh, J.W., Chun, D.W., Kim, S., Jung, S.H., Kang, H.K., Jeong, W.Y., Lee, W.: Perpendicular magnetic anisotropy in FePt patterned media employing a CrV seed layer. Nanoscale Res. Lett. 6(1), 1 (2010)
- 38.
Lai, Y.C., Chang, Y.H., Chen, Y.C., Liang, C.H., Chang, W.C., Chiou, C.M., Chen, G.J.: Inductive magnetization of low-temperature ordered L10-FePt with CoAg underlayer. J. Appl. Phys. 101(5), 053913 (2007)
- 39.
Sun, H.Y., Xu, J.L., Feng, S.Z., Su, Z.F., Hu, J., Sun, Y.P.: Magnetic properties and microstructures of FePt/Ti bilayer films sputter deposited onto glass amorphous substrates. Appl. Phys. Lett. 88(19), 2501 (2006)
- 40.
Lin, J.J., Zhang, T., Lee, P., Springham, S.V., Tan, T.L., Rawat, R.S., White, T., Ramanujan, R., Guo, J.: Magnetic trapping induced low temperature phase transition from fcc to fct in pulsed laser deposition of FePt: Al2 O 3 nanocomposite thin films. Appl. Phys. Lett. 91(6), 063120 (2007)
- 41.
Chang, H.W., Yuan, F.T., Yuan, C.W., Yu, C.H., Wang, C.R., Chang, W.C.: Effect of magnetic field on the structure and magnetic properties of pulse-laser-deposited FePt films. J. Alloys Compd. 584, 148–151 (2014)
- 42.
Sternik, M., Couet, S., ŁaŻewski, J., Jochym, P.T., Parlinski, K., Vantomme, A., Temst, K., Piekarz: Dynamical properties of ordered FePt alloys. J. Alloys Compnd. 651, 528–536 (2015)
- 43.
Kaushik, N., Sharma, P., Yubuta, K., Makino, A., Inoue, A.: Domain wall assisted magnetization switching in (111) oriented L10 FePt grown on a soft magnetic metallic glass. Appl. Phys. Lett. 97(7), 072510–3 (2010)
- 44.
Dannenberg, A., Gruner, M.E., Hucht, A., Entel, P.: Surface energies of stoichiometric FePt and CoPt alloys and their implications for nanoparticle morphologies. Phys. Rev. B 80(24), 245438 (2009)
- 45.
Cullity, B.D., Stock, S.R.: Elements of X-ray diffraction, pp 1–664. Prentice Hall Inc., New Jersey (2001)
- 46.
Kim, J.S., Koo, Y.M., Lee, B.J., Lee, S.R.: The origin of (001) texture evolution in FePt thin films on amorphous substrates. J. Appl. Phys. 99(5), 053906 (2006)
- 47.
Goswami, R., Cheng, S.F., Qadri, S.B., Oh, E., Bussmann, K.: TEM studies of microstructure, interfaces, and intermixing of FePt/MgO/FePt/Pt/Cr (Ru) films. J. Nanoparticle Res. 15(4), 1–7 (2013)
- 48.
Chen, S.C., Kuo, P.C., Kuo, S.T., Sun, A.C., Lie, C.T., Chou, C.Y.: Effects of Ti underlayer on the degree of order of Fe50Pt50 films. Mater. Sci. Eng. B 98(3), 244–247 (2003)
- 49.
Shima, T., Moriguchi, T., Mitani, S., Takanashi, K.: Low-temperature fabrication of L10 ordered FePt alloy by alternate monatomic layer deposition. Appl. Phys. Lett. 80(2), 288–290 (2002)
- 50.
Granz, S.D., Kryder, M.H.: Granular L10 FePt (001) Thin films for heat assisted magnetic recording. J. Magn. Magn. Mater. 324(3), 287–294 (2012)
- 51.
Barmak, K., Wang, B., Jesanis, A.T., Berry, D.C., Rickman, J.M.: L10 FePt: Ordering, anisotropy constant and their relation to film composition. IEEE Trans. Magn. 49(7), 3284–3291 (2013)
- 52.
Hsiao, S.N., Liu, S.H., Chen, S.K., Lee, H.Y.: Effect of annealing process on strain-induced crystallographic orientation of FePt thin films. IEEE Trans. Magn. 48(11), 4014–4017 (2012)
- 53.
Yang, E., Laughlin, D.E., Zhu, J.G.: Correction of order parameter calculations for FePt perpendicular thin films. IEEE Trans. Magn. 48(1), 7–12 (2012)
- 54.
Weisheit, M., Schultz, L., Fähler, S.: Textured growth of highly coercive L10 ordered FePt thin films on single crystalline and amorphous substrates. J. Appl. Phys. 95(11), 7489–7491 (2004)
- 55.
Brune, H.: Microscopic view of epitaxial metal growth: nucleation and aggregation. Surf. Sci. Rep. 31(4), 125–229 (1998)
- 56.
Dong, K.F., Jin, F., Mo, W.Q., Song, J.L., Cheng, W.M.: Improvement of isolation and grain size of FePt-SiNx-C films with TiON intermediate layer. J. Alloys Compd. 662, 138–142 (2016)
- 57.
Kim, C.S., Sapan, J.J., Moyerman, S., Lee, K., Fullerton, E.E., Kryder, M.H.: Thickness and temperature effects on magnetic properties and roughness of ordered FePt films. IEEE Trans. Magn. 46(6), 2282–2285 (2010)
- 58.
Floro, J.A., Hearne, S.J., Hunter, J.A., Kotula, P., Chason, E., Seel, S.C., Thompson, C.V: The dynamic competition between stress generation and relaxation mechanisms during coalescence of Volmer–Weber thin films. J. Appl. Phys. 89(9), 4886–4897 (2001)
- 59.
Thornton, J.A.: Influence of substrate temperature and deposition rate on structure of thick sputtered Cu coatings. J. Vac. Sci. Technol. 12(4), 830–835 (1975)
- 60.
Christodoulides, J.A., Bonder, M.J., Huang, Y., Zhang, Y., Stoyanov, S., Hadjipanayis, G.C., Simopoulos, A., Weller, D.: Intrinsic and hysteresis properties of FePt nanoparticles. Phys. Rev. B 68(5), 054428 (2003)
- 61.
Ahn, S.M., Beach, G.S.D.: Crossover between in-plane and perpendicular anisotropy in Ta/CoxFe100−x/MgO films as a function of Co composition. J. Appl. Phys. 113(17), 17C112 (2013)
- 62.
Honda, N., Ouchi, K., Iwasaki, S.I.: Design consideration of ultrahigh-density perpendicular magnetic recording media. IEEE Trans. Magn. 38(4), 1615–1621 (2002)
- 63.
Tagawa, I., Takeo, A., Nakamura, Y.: Numerical analysis of noise and inter-particle interaction in perpendicular magnetic recording media. J. Magn. Magn. Mater. 155(1), 341–344 (1996)
Author information
Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mokhtari, P., Kameli, P., Ehsani, M.H. et al. Microstructure and Magnetic Properties of FePt Thin Films on SiO2/Si (100) and Si Substrates Prepared Under External Magnetic Field. J Supercond Nov Magn 30, 1949–1961 (2017). https://doi.org/10.1007/s10948-017-3998-4
Received:
Accepted:
Published:
Issue Date:
Keywords
- FePt thin film
- Pulsed laser deposition
- Coercivity
- Surface morphology