Abstract
In this paper, Li0.43Zn0.27Ti0.13Fe2.17O4-xBaTiO3 composite materials (x = 0 wt%, 2 wt%, 4 wt%, 6 wt%, 8 wt%, 10 wt%) were prepared and the structure and properties were investigated. The result of X-ray diffraction (XRD) revealed that the composites contained two phase formations, with no other phases. Scanning electron microscopy (SEM) images showed that the size of grains decreased gradually with x increasing, and the densification was enhanced by adding BaTiO3 (BT) material. The magnetic permeability and dielectric permittivity of the samples were characterized. With increasing values of x, the real part of magnetic permeability μ decreased from 110 to 15 and the magnetic loss (tanδ μ ) remained at a low value. In addition, the real part of the dielectric permittivity increased first from 30 to 65 and then decreased after x = 6 wt%, and the dielectric loss (tanδ) reached the lowest value at x = 6 wt%. This material had a potential application in filter devices.
Similar content being viewed by others
References
Zeng, H., Tao, T., Wu, Y., Qi, W., Kuang, C., Zhou, S., et al.: Lithium ferrite (Li0.5Fe2.5O4) nanoparticles as anodes for lithium ion batteries. RSC Adv. 4, 23145 (2014)
Zhou, T.C., Zhang, H.W., Jia, L.J., Liao, Y.L., Zhong, Z.Y., Bai, F.M., et al.: Enhanced ferromagnetic properties of low temperature sintering LiZnTi ferrites with Li2O-B2O3-SiO2-CaO-Al2O3 glass addition. J. Alloys Compd. 620, 421–6 (2015)
Guo, R., Yu, Z., Yang, Y., Jiang, X., Sun, K., Wu, C., et al.: Effects of Bi2O3 on FMR linewidth and microwave dielectric properties of LiZnMn ferrite. J. Alloys Compd. 589, 1–4 (2014)
Jiang, H., Guo, J., Zhao, L., Zhu, H.: Preparation and microwave absorption properties of LiZn ferrite. J. Inorg. Mater. 25, 73–6 (2010)
Liao, Y.L., Xu, F., Zhang, D.N., Zhou, T.C., Wang, Q., Wang, X.Y., et al.: Low temperature firing of Li0.43Zn0.27Ti0.13Fe2.17O4 ferrites with enhanced magnetic properties. J. Am. Ceram. Soc. 98, 2556–60 (2015)
Dash, J., Prasad, S., Venkataramani, N., Krishnan, R., Kishan, P., Kumar, N., et al.: Study of magnetization and crystallization in sputter deposited LiZn ferrite thin films. J. Appl. Phys. 86, 3303–11 (1999)
Sun, C., Sun, K.N.: Synthesis and characterization of LiZn ferrite-coated CNT via a sol-gel method. Adv. Compos. Lett. 15, 169–72 (2006)
Song, Y.Y., Grinolds, M.S., Krivosik, P., Patton, C.E.: Pulsed laser-deposited single-crystal LiZn-ferrite films with low microwave loss. J. Appl. Phys., 97 (2005)
Xiang, J., Chu, Y.Q., Zhou, G.Z., Guo, Y.T., Guo, J.Y., Shen, X.Q.: Electrospinning preparation, structural and magnetic properties of Li0.5−0.5xZnxFe2.5−0.5xO4 nanofibers. Acta Chim. Sin. 69, 2457–64 (2011)
Misra, S., Ram, S.: Effect of Zn 2+ > Li +Fe 3+ substitution on electromagnetic properties in lithium zinc ferrite. In: 2013 International Conference on Microwave and Photonics (Icmap) (2013)
Saxena, N.K., Kumar, N., Pourush, P.K.S., Khah, S.K.: Study of magnetic properties of substituted LiTiZn-ferrite for microwave antenna applications. Optoelectron. Adv. Mat. 4, 328–31 (2010)
Saxena, N.K., Singh, B., Kumar, N., Pourush, P.K.S.: Microstrip triangular patch antenna fabricated on LiTiZn ferrite substrate and tested in the X band range. Aeu-Int. J. Electron. C. 66, 140–2 (2012)
Sharma, S., Tomar, M., Kumar, A., Puri, N.K., Gupta, V.: Multiferroic properties of BiFeO3/BaTiO3 multilayered thin films. Phys. B Condens. Matter 448, 125–7 (2014)
Fu, C.L., Cai, W., Deng, X.L.: Microstructure and dielectric properties of BaTiO3-based ferroelectric materials. Mater. Sci. Forum 687, 133–7 (2011)
Guillemet-Fritsch, S., Valdez-Nava, Z., Tenailleau, C., Lebey, T., Durand, B., Chane-Ching, J.Y.: Colossal permittivity in ultrafine grain size BaTiO3−x and Ba0.95La0.05TiO3−x materials. Adv. Mater. 20, 551 (2008)
Abe, K., Kitahara, N., Higuchi, M., Takahashi, J.: Permittivity change of NiZn ferrite–BaTiO3 composites with Fe content. Jpn. J. Appl. Phys. 48, 09KC4 (2009)
Wang, X., Li, Y., Li, J., Yu, G., Zuo, L., Zhang, H.: Effect of BiVO4 doping on the magnetic properties and microstructure of NiCuZn ferrites. J. Mater. Sci. Mater. Electron. 25, 4230–4 (2014)
Acknowledgments
This work was supported by the Open Foundation of National Engineering Research Center of Electromagnetic Radiation Control Materials (No. ZYGX2014K003-8) and the National Natural Science Foundation of China under Grant Nos. 61271038 and 51472042.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Gao, Y., Zhang, H., Li, Y. et al. Magnetic and Dielectric Properties of Li0.43Zn0.27Ti0.13Fe2.17O4-xBaTiO3 Composite Materials. J Supercond Nov Magn 29, 965–969 (2016). https://doi.org/10.1007/s10948-016-3391-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10948-016-3391-8