Abstract
Nanocrystalline Ni1−x Zn x Fe1.5Cr0.5O4 (0 ≤ x ≤ 0.5) ferrite was prepared using a citrate method. The influence of Zn2+ ion substitution on structure, magnetic, and electric properties of the Ni1−x Zn x Fe1.5Cr0.5O4 ferrite has been investigated. The X-ray diffraction results confirmed the formation of a single phase with a spinel cubic structure for Ni1−x Zn x Fe1.5Cr0.5O4 samples. The magnetization was found to be influenced by the surface spin canting angles, the porosity percentage, and the cation distributions. The variation of dielectric constant with temperature indicated that the investigated materials can be recommended to be used as good insulating ceramic materials at room temperature and as a semiconductor at higher temperatures.
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References
Goldman, A. Modern ferrite technology, 2nd edn. Springer, New York (2006)
Shirsath, S.E., Jadhav, S.S., Toksha, B.G., Patange, S.M., Jadhav, K.M.: Scripta Mater. 64, 773 (2011)
Sertkol, M., Koseoglu, Y., Baykal, A., Kavas, H., Bozkurt, A., Toprak, M.S.: J. Alloy. Comp. 1, 325 (2009)
Heiba, Z.K., Mohamed, M.B., Ahmed, M.A., Moussa, M.A.A., Hamdeh, H.H.: J. Alloy. Comp 586, 773 (2014)
Heiba, Z.K., Mohamed, M.B., Hamdeh, H.H., Ahmed, M.A.: J. Alloy. Comp. 618, 755 (2015)
Mitchell, B.S.: An introduction to materials engineering and science for chemical and materials engineers Wiley, Hoboken
Pradhan, S.K., Bidb, S., Gateshki, M., Petkov, V.: Mater. Chem. Phys 93, 224 (2005)
Jacob, B.P., Kumar, A., Pant, R.P., Singh, S., Mohamed, E.M.: Bull. Mater. Sci 34, 1345 (2011)
Muhammed, T., Yuksel, K., Furkan, A., Enturk, S.E.: J. Alloy Comp 509, 9399 (2011)
Mohamed, M.B., El-Sayed, K.: Compos. B: Eng. 56, 270 (2014)
Mohamed, M.B., El-Sayed, K.: Mater. Res. Bull 48, 1778 (2013)
Lutterotti, L.: Maud 2.33, http://www.ing.unitn.it/%7Emaud/
Popa, N.C.: J. Appl. Cryst 31, 176 (1988)
Rodriguez-Carvajal, J.: Physica B. (Amsterdam) 192, 55 (1993)
Weil, L., Bertaut, E.F., Bochirol, L.: J. Phys. Radium 11, 208 (1950)
Buerger, M.J. Crystal structure analysis. Wiley, New York (1960)
Cullity, B.D.: The elements of X-ray diffraction. Addison Wesley, Reading (1956)
Wahba, A.M., Mohamed, M.B.: Ceram. Int. 40, 6127 (2014)
Wang, Q., Saunders, G.A., Almond, D.P., Cankurtaran, M., Goretta, K.C.: Phys. Rev. B 52, 3711e3726 (1995)
Kodama, R.H., Berkowitz, A.E., McNiff, E.J., Foner, S.: Phys. Rev. Lett. 77, 394 (1996)
Younas, M., Nadeem, M., Atif, M., Grossinger, R.: J. Appl. Phys 109, 093704 (2011)
Kushwaha, A., Tyagi, H., Aslam, M.: AIP Advances 3, 042110 (2013)
Xie, Q.Y., Gu, M.Q., Huang, L., Zhang, F.M., Wu, X.S.: AIP Advances 2, 012185 (2012)
Jonscher, A.K.J.: Dielectric relaxation in solids. Chelsca Dielectric Press Limited, London (1986)
Verma, K., Kumar, A., Varshney, D.: Curr. Appl. Phys. 13, 467 (2013)
Farea, A.M.M., Kumar, S., Batoo, K.M., Yousef, A., Lee, C.G.: Alimuddin J. Alloy. Comp. 464, 361 (2008)
Groothues, H., Kremer, F., Schouten, P.G., Warman, J.M.: Adv. Mater. 7, 283 (1995)
Long, A.R.: Adv. Phys. 31, 553 (1982)
Pike, G.E.: Phys. Rev. B 6, 1572 (1972)
Elliot, S.R.: Philos. Mag. B 36, 1291 (1977)
Shimakawa, K.: Philos. Mag. B 46, 123 (1982)
Shimakawa, K.: Philos. Mag. B 48, 778 (1983)
Ghosh, A.: Phys. Rev. B 41, 1479 (1990)
Groothues, H., Kremer, F., Schouten, P.G., Warman, J.M.: Adv. Mater. 7, 283 (1995)
Sivakumar, N., Narayanasamy, A., Ponpandian, N., Govindaraj, G.: J. Appl. Phys. 101, 084116 (2007)
Varshney, D., Verma, K.: Mater. Chem. Phys. 140, 412e418 (2013)
Murugavel, S., Upadhay, M.: J. Indian Inst. Sci. 91, 303 (2011)
Isard, J.O.: J. Non-Cryst. Solids 4, 357 (1970)
Namikswa, H.: J. Non-Cryst. Solids 18, 173 (1975)
Verma, A., Thakur, O.P., Prakash, C., Goel, T.C., Mendiratta, R.G.: Mater. Sci. Eng. B 116, 1 (2005)
Maxwell, J.C.: Electricity and magnetism, vol. 2, p. 828. Oxford University Press, New York (1973)
Wagner, K.W.: Am. J. Phys. 40, 817 (1993)
Koops, C.G.: Phys. Rev. 83, 121 (1951)
Macdonald, J.R.: Impedance spectroscopy: emphasizing solid materials and systems. Wiley, New York (1987)
Sivakumar, N., Narayanasamy, A., Ponpandian, N., Greneche, J.M., Shinoda, K., Jeyadevan, B., Tohji, K.: J. Phys. D: Appl. Phys. 39, 4688 (2006)
Rezlescu, N., Rezlescu, E.: Phys. Status Solidi A 23, 575 (1974)
Irvine, J.T.S., Huanosta, A., Velenzuela, R., West, A.R.: J. Am. Ceram. Soc., 73 (1990)
Van Uitert, L.G.: J. Chem. Phys. 23, 1883 (1955)
Varshney, D., Verma, K.: Mater. Chem. Phys 140, 412–418 (2013)
Gopalan, V.E., Malini, K.A., Saravanan, S., Sakthi, K.D., Yoshida, Y., Anantharaman, M.R.: J. Phys. D Appl. Phys. 185005, 41 (2008)
Murase, T., Igarahi, K., Sawai, J.: Nomura, ICF 7, B 3, Bordeaux (France) (1996)
Inaba, H.: J. Mater. Sci. 32, 1867 (1997)
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Mohamed, M.B., El-Sayed, K. Structure and Microstructure in Relation to Magnetic/Dielectric Properties of Nanocrystalline Ni1−x Zn x Fe1.5Cr 0.5O4 Ferrite. J Supercond Nov Magn 28, 2121–2131 (2015). https://doi.org/10.1007/s10948-015-3013-x
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DOI: https://doi.org/10.1007/s10948-015-3013-x