Abstract
The crystal structure and magnetic properties of single phase Pr1−x Gd x Co4Si compounds with x=0,0.2,0.4,0.6,0.8, and 1.0 have been investigated. X-ray analysis reveals that the compounds crystallize as a single phase having the hexagonal CaCu5-type structure with the space group P6/mmm. The substitution of Gd for Pr causes a linear decrease of the unit-cell parameters a and c, and the unit-cell volume V. Magnetic measurements indicate that all samples are ordered magnetically below the Curie temperature. The saturation magnetization at 4.2 K decreases upon the Gd substitution up to x=0.6, and then increases.
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Liu, J.P., de Boer, F.R., de Chatel, P.F., Coehoorn, R., Buschow, K.H.J.: J. Magn. Magn. Mater. 132, 159 (1994)
Kirchmayr, H.R., Poldy, C.A.: In: Gschneidner, K., Eyring, L. (eds.) Handbook on the Physics and Chemistry of Rare Earths, vol. 2. Elsevier, Amsterdam (1979) (Chap. 14)
Hong, N.M., Holubar, T., Hilscher, G., Vybornov, M., Rogl, P.: IEEE Trans. Magn. 30, 4966 (1994)
Nagarajan, R., Gupta, L.C., Mazumdar, C., Hossain, Z., Dhar, S.K., Godart, C., Padalia, B.D., Vijayaraghavan, R.: J. Alloys Compd. 225, 571 (1995)
Kirchmayr, H.R.: J. Phys. D, Appl. Phys. 29, 2763 (1996)
Oesterreicher, H., Parker, F.T., Mishroch, M.: Phys. Rev. B 18(1), 480 (1978)
Pecharsky, V.K., Gschneidner, K.A.: J. Magn. Magn. Mater. 200, 44 (1999)
Novak, P., Kuriplach, J., et al.: Phys. Rev. B 50, 2085 (1994)
Coldea, M., Andreica, D., Bitu, M., Crisan, V.: J. Magn. Magn. Mater. 157–158, 627 (1996)
Zlotea, C., Isnard, O.: J. Alloys Compd. 346, 29 (2002)
Klosek, V., Zlotea, C., Isnard, O.: J. Phys. Condens. Matter 15, 8327 (2003)
Burzo, E., Plugaru, N., Creangǎ, I., Ursu, M.: J. Less-Common Met. 155, 281 (1989)
Mincic, A.: J. Phys. Condens. Matter 16, 1837 (2004)
Thang, C.V., Nam, L.H., Duong, N.P., Thuy, N.P., Brück, E.: J. Magn. Magn. Mater. 196(197), 765 (1999)
Coroian, N., Isnard, O., Roşu, D., Pop, V.: Rom. Rep. Phys. 58, 173 (2006)
Rodriguez-Carvajal, J.: Physica B 192, 55 (1993)
Kervan, N., Kervan, S., Sözeri, H.: Mater. Chem. Phys. 120, 505 (2010)
Kervan, S., Acet, M., Elerman, Y.: Solid State Commun. 119, 95 (2001)
Burzo, E., Creanga, I., Plugaru, N., Pop, V., Ursu, M.: Rev. Roum. Phys. 33, 57 (1988)
Campbell, I.A.: J. Phys. F, Met. Phys. 2, L47 (1972)
Tolinski, T., Kowalczyk, A., Szlaferek, A., Timko, M., Kovac, J.: Solid State Commun. 122, 363 (2002)
Kervan, N., Kervan, S., Gencer, A.: J. Phys. Chem. Solids 69, 2791 (2008)
Kervan, N., Kervan, S., Gencer, A.: J. Magn. Magn. Mater. 320, 2839 (2008)
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Kervan, N., Kervan, S. & Sözeri, H. Gd Substitution Effects on the Magnetic Properties of the Pr1−x Gd x Co4Si Compounds. J Supercond Nov Magn 26, 703–707 (2013). https://doi.org/10.1007/s10948-012-1789-5
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DOI: https://doi.org/10.1007/s10948-012-1789-5