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Structure of the surface layer of mercury and adhesion of Langmuir monolayers on it

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Abstract

A model crystalline approximant of the surface layer (SL) structure of liquid mercury is formed using the algorithm, previously applied to form a crystalline approximant of the SL structure of water, the experimental data on the SL structure of mercury, and the stereochemical data for Hg atoms in the α-Hg crystalline phase and bulk liquid mercury. The correspondence of the metrics of the crystalline approximant proposed for the SL structure of mercury and Langmuir monolayers composed of organic molecules with hydrocarbon tails and different hydrophilic groups on liquid mercury to the position of molecules along mercury SL is shown.

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References

  1. S. Mann, Nature, 365, 499–505 (1993).

    Article  CAS  Google Scholar 

  2. M. Stoneham, Rep. Prog. Phys., 70, 1055–1097 (2007).

    Article  CAS  Google Scholar 

  3. N. A. Bulienkov and E. A. Zheligovskaya, Zh. Fiz. Khim., 80, No. 10, 1784–1805 (2006).

    Google Scholar 

  4. N. A. Bulienkov, Biofizika, 36, No. 2, 181–243 (1991).

    Google Scholar 

  5. N. A. Bulienkov and V. V. Klechkovskaya, Theses for the 3 National Conf. on the Application of X-ray, Synchrotron Radiations, Neutrons and Electrons to Study Materials (RSNE-2001) [in Russian], Moscow, May 21–25 (2001), p. 195.

  6. V. V. Klechkovskaya, N. A. Bulienkov, and E. A. Zheligovskaya, Theses for the 6 National Conf on the Application of X-ray, Synchrotron Radiations, Neutrons and Electrons to Study Materials (RSNE-2001) [in Russian], Moscow, November 12–17 (2007), p. 201.

  7. N. A. Bulienkov and E. A. Zheligovskaya, Theses for the 3 Intern. Conf. on Colloidal Chemistry and Physicochemical Mechanics [in Russian], Moscow, June 24–28 (2008), p. 21.

  8. O. Shpyrko, M. Fukuto, P. Pershan, et al, Phys. Rev. B, 69, No. 24, 245423(l)–245423(5) (2004).

    Article  Google Scholar 

  9. O. M. Magnussen, B. M. Ocko, M. J. Regan, et al, Phys. Rev. Lett., 74, No. 22, 4444–4447 (1995).

    Article  CAS  Google Scholar 

  10. M. J. Regan, E. H. Kawamoto, S. Lee, et al, ibid., 75, No. 13, 2498–2501 (1995).

    Article  CAS  Google Scholar 

  11. H. Tostmann, E. DiMasi, P. S. Pershan, et al, Phys. Rev. B, 59, No. 2, 783–791 (1999).

    Article  CAS  Google Scholar 

  12. O. G. Shpyrko, A. Yu. Grigoriev, C. Steimer, et al, ibid., 70, No. 22, 224206(1)–224206(7) (2004).

    Article  Google Scholar 

  13. O. Shpyrko, P. Huber, A. Grigoriev, et al, ibid., No. 11, 115405(1)–115405(7) (2003).

    Google Scholar 

  14. E. Sloutskin, B. M. Ocko, L. Tamam, et al., J. Am. Chem. Soc, 127, No. 21, 7796–7804 (2005).

    Article  Google Scholar 

  15. H. Mo, G. Evmenenko, S. Kewalramani, et al, Phys. Rev. Lett., 96, No. 9, 096107(1)–096107(4) (2006).

    Article  Google Scholar 

  16. J. D. Bernai, Crystallography, I, No. 4, 507–519 (1962).

    Google Scholar 

  17. H. Kraack, B. M. Ocko, P. S. Pershan, et al, Science, 298, 1404–1407 (2002).

    Article  CAS  Google Scholar 

  18. H. Kraack, B. M. Ocko, P. S. Pershan, et al, Langmuir., 20, No.13, 5375–5385 (2004).

    Article  CAS  Google Scholar 

  19. H. Kraack, B. M. Ocko, P. S. Pershan, et al, J. Chem. Phys., 119, No. 19, 10339–10349 (2003).

    Article  CAS  Google Scholar 

  20. B. M. Ocko, H. Kraack, P. S. Pershan, et al, Phys. Rev. Lett, 94, No. 1, 017802(l)–017802(4) (2005).

    Article  Google Scholar 

  21. H. Kraack, B. M. Ocko, P. S. Pershan, et al, Langmuir., 20, No. 13, 5386–5395(2004).

    Article  CAS  Google Scholar 

  22. L. Bosio, R. Cortes, and C. Segaud, J. Chem. Phys., 71, No. 9, 3595–3600 (1979).

    Article  CAS  Google Scholar 

  23. N. Camellone, P. Eisenberger, T. Y. B. Leung, et al, ibid., 101, No. 12, 11031–11036 (1994).

    Article  Google Scholar 

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Authors and Affiliations

  1. A. V. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Moscow, Russia

    N. A. Bulienkov, E. A. Zheligovskaya & V. V. Klechkovskaya

  2. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    N. A. Bulienkov & E. A. Zheligovskaya

Authors
  1. N. A. Bulienkov
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  2. E. A. Zheligovskaya
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  3. V. V. Klechkovskaya
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Correspondence to N. A. Bulienkov.

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Original Russian Text Copyright © 2009 by N. A. Bulienkov, E. A. Zheligovskaya, and V. V. Klechkovskaya

Translated from Zhurnal Strukturnoi Khimii, Vol. 50, Supplement, pp. S93–S99, 2009.

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Bulienkov, N.A., Zheligovskaya, E.A. & Klechkovskaya, V.V. Structure of the surface layer of mercury and adhesion of Langmuir monolayers on it. J Struct Chem 50 (Suppl 1), 86–92 (2009). https://doi.org/10.1007/s10947-009-0194-9

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  • DOI: https://doi.org/10.1007/s10947-009-0194-9

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