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Crystal structure of [(C5Me4Et)3Rh3(μ3-Se)2](PF6)2CH3CN and [(C5Me4Et)2Rh2(μ2-Cl)3]PF6

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Abstract

The crystal structure of [(C5Me4Et)3Rh3(μ3-Se)2](PF6)2 and [(C5Me4Et)2Rh2(μ2-Cl)3]PF6, obtained in the reaction of [(C5Me4Et)Rh(C6H6)](PF6)2 with ZnSe in 4M HCl under hydrothermal conditions, is determined. In agreement with the 18VE rule, the triangular cluster contains single metal-metal bonds (Rh-Rh 2.864(1) Å), whereas they are absent in the binuclear complex (Rh ...Rh 3,216(1) Å).

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Abramov, M. N. Sokolov, A. V. Virovets & V. P. Fedin

  2. Novosibirsk State University, Novosibirsk, Russia

    M. N. Sokolov & V. P. Fedin

Authors
  1. P. A. Abramov
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  2. M. N. Sokolov
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  3. A. V. Virovets
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  4. V. P. Fedin
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Correspondence to P. A. Abramov.

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Original Russian Text Copyright © 2009 by P. A. Abramov, M. N. Sokolov, A. V. Virovets, and V. P. Fedin

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Translated from Zhurnal Strukturnoi Khimii, Vol. 50, No. 1, pp. 169–172, January–February, 2009.

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Abramov, P.A., Sokolov, M.N., Virovets, A.V. et al. Crystal structure of [(C5Me4Et)3Rh3(μ3-Se)2](PF6)2CH3CN and [(C5Me4Et)2Rh2(μ2-Cl)3]PF6 . J Struct Chem 50, 162–165 (2009). https://doi.org/10.1007/s10947-009-0022-2

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  • DOI: https://doi.org/10.1007/s10947-009-0022-2

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