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Crystal structure and luminescence of antimony(III) chloride complex with anilinium chloride

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Abstract

Crystal structure of (C6H5NH3)3[SbCl5]Cl·H2O is determined by X-ray analysis (a = 9.4155(13) Å, b = 11.4344(16) Å, c = 13.1584(18) Å, α = 113.483(2)°, β = 90.383(2)°, γ = 97.323(2)°, space group P \( \bar 1 \), Z = 2, ρcalc = 1.642 g/cm3). The crystal structure is based on [SbCl5]2− anions, anilinium cations (C6H5NH3)+, isolated Cl− anions, and water molecules. Structural features responsible for spectral and luminescent properties of the complex are discussed.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok, Russia

    B. V. Bukvetskii, T. V. Sedakova & A. G. Mirochnik

Authors
  1. B. V. Bukvetskii
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  2. T. V. Sedakova
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  3. A. G. Mirochnik
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Correspondence to A. G. Mirochnik.

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Original Russian Text Copyright © 2009 by B. V. Bukvetskii, T. V. Sedakova, and A. G. Mirochnik

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Translated from Zhurnal Strukturnoi Khimii, Vol. 50, No. 1, pp. 156–159, January–February, 2009.

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Bukvetskii, B.V., Sedakova, T.V. & Mirochnik, A.G. Crystal structure and luminescence of antimony(III) chloride complex with anilinium chloride. J Struct Chem 50, 149–152 (2009). https://doi.org/10.1007/s10947-009-0019-x

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  • DOI: https://doi.org/10.1007/s10947-009-0019-x

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