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Journal of Structural Chemistry

, Volume 50, Issue 1, pp 149–152 | Cite as

Crystal structure and luminescence of antimony(III) chloride complex with anilinium chloride

  • B. V. Bukvetskii
  • T. V. Sedakova
  • A. G. MirochnikEmail author
Article

Abstract

Crystal structure of (C6H5NH3)3[SbCl5]Cl·H2O is determined by X-ray analysis (a = 9.4155(13) Å, b = 11.4344(16) Å, c = 13.1584(18) Å, α = 113.483(2)°, β = 90.383(2)°, γ = 97.323(2)°, space group P \( \bar 1 \), Z = 2, ρcalc = 1.642 g/cm3). The crystal structure is based on [SbCl5]2− anions, anilinium cations (C6H5NH3)+, isolated Cl anions, and water molecules. Structural features responsible for spectral and luminescent properties of the complex are discussed.

Keywords

crystal structure antimony(III) aniline luminescence 

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Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • B. V. Bukvetskii
    • 1
  • T. V. Sedakova
    • 1
  • A. G. Mirochnik
    • 1
    Email author
  1. 1.Institute of Chemistry, Far East DivisionRussian Academy of SciencesVladivostokRussia

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