Abstract
Binary complex salts [Ru(NH3)5Cl][ReCl6] and [Ru(NH3)5Cl]2[ReCl6]Cl2 were synthesized and characterized. An X-ray diffraction analysis showed that they were isostructural with the previously obtained isoformula salts [Rh(NH3)5Cl][OsCl6] and [Ir(NH3)5Cl]2[PtCl6]Cl2, respectively. Thermolysis of these compounds under hydrogen and helium was studied. According to X-ray phase analysis data, bimetallic solid solutions Ru0.67Re0.33 and Ru0.50Re0.50 were the final products of thermolysis. Their unit cell parameters correspond to the characteristics of alloys with similar compositions.
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Original Russian Text Copyright © 2009 by S. A. Martynova, K. V. Yusenko, I. V. Korolkov, I. A. Baidina, and S. V. Korenev
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Translated from Zhurnal Strukturnoi Khimii, Vol. 50, No. 1, pp. 126–132, January–February, 2009.
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Martynova, S.A., Yusenko, K.V., Korolkov, I.V. et al. X-ray diffraction study of [Ru(NH3)5Cl][ReCl6] and [Ru(NH3)5Cl]2[ReCl6]Cl2 and their thermolysis products. Crystal-chemical analysis of the Ru-Re system. J Struct Chem 50, 120–126 (2009). https://doi.org/10.1007/s10947-009-0016-0
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DOI: https://doi.org/10.1007/s10947-009-0016-0