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Crystal structures of sulfathiazole polymorphs in the temperature range 100–295 K: A comparative analysis

Journal of Structural Chemistry volume 49, pages 84–94 (2008)Cite this article

Abstract

The response of four polymorph modifications of sulfathiazole C9H9N3O2S2 to variation of temperature was examined in the range 295–100 K by single crystal X-ray diffraction. No phase transitions occur in this temperature range; all the structures exhibit anisotropic contraction. The metastable sulfathiazole modification I is drastically different from the other modifications (II, III, and IV) in the anisotropy of structure distortions and changes in the intra-and intermolecular geometry, although bulk thermal expansion is virtually similar for all polymorphs within the temperature range studied.

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Authors and Affiliations

  1. Institute of Solid State Chemistry and Mechanochemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    T. N. Drebushchak, E. V. Boldyreva & M. A. Mikhailenko

  2. Novosibirsk State University, Research and Education Center for Molecular Design and Ecologically Safe Technologies, Russia

    T. N. Drebushchak, E. V. Boldyreva & M. A. Mikhailenko

Authors
  1. T. N. Drebushchak
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  2. E. V. Boldyreva
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  3. M. A. Mikhailenko
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Correspondence to T. N. Drebushchak.

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Original Russian Text Copyright © 2008 by T. N. Drebushchak, E. V. Boldyreva, and M. A. Mikhailenko

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 49, No. 1, pp. 90–100, January–February, 2008.

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Drebushchak, T.N., Boldyreva, E.V. & Mikhailenko, M.A. Crystal structures of sulfathiazole polymorphs in the temperature range 100–295 K: A comparative analysis. J Struct Chem 49, 84–94 (2008). https://doi.org/10.1007/s10947-008-0013-8

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  • DOI: https://doi.org/10.1007/s10947-008-0013-8

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