Abstract
Nickel-doped alkali halide microcrystals were obtained by various methods, including an original synthetic procedure. Their spectral and structural characteristics were investigated. The crystal field strength was calculated from the reflection spectra recorded for the microcrystals for different impurity concentrations. In contrast to single crystals, higher impurity concentrations can be obtained for lower degrees of aggregation in microcrystals.
Similar content being viewed by others
References
M. J. Weber, J. Luminesc., 100, Nos. 1–4, 35–45 (2002).
V. I. Kochubey and Yu. G. Konyukhova, J. X-ray Science Technol., 13, No. 4, 199–208 (2005).
V. I. Kochubey, Yu. G. Konyukhova, and D. I. Kochubey, ibid., 10, Nos. 3/4, 199–214 (2002).
G. B. Gorin, K. E. Guynsburg, N. P. Zvezdova, et al., Nucl. Instr. Meth. Phys. Res. A, 448, Nos. 1/2, 196–199 (2000).
J.-M. Spaeth, Rad. Meas., 33, No. 5, 527–532 (2001).
J. Freudenberger, E. Hell, and W. Knüpfer, Nucl. Instr. Meth. Phys. Res. A, 466, No. 1, 99–104 (2001).
D. A. Zimnyakov, Yu. P. Sinichkin, I. V. Kiseleva, and D. N. Agafonov, Opt. Spektrosk., 92, No. 5, 848–855 (2002).
V. N. Sidelnikov, L. V. Gur’yanova, V. A. Utkin, and V. V. Malakhov, Catalog of Abbreviated Mass Spectra [in Russian], Nauka, Novosibirsk (1981).
K. Waizumi, T. Kouda, A. Tanio, et al., J. Sol. Chem., 28, No. 2, 83–100 (1999).
V. I. Kochubei, “Formation and properties of luminescence centers in alkali halide crystals doped with elements from Groups IIIA and VIIIB,” Physical and Mathematical Sciences Doctoral Dissertation, Saratov (2002).
D. Nowak-Wozny, M. Suszynska, M. Szmida, and R. Capeletti, J. Mater. Sci., 28, No. 3, 645–648 (1993).
I. Foldvari, R. Voszka, and Z. Morlin, Phys. Status Solidi (b), 89, 235–240 (1978).
A. B. P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam (1984).
T. Nasu and Y. Asano, J. Phys. Soc. Jpn., 27, No. 1, 263 (1969).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text Copyright © 2007 by Yu. G. Konyukhova, V. I. Kochubei, D. I. Kochubei, and V. P. Babenko
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No. 6, pp. 1164–1169, November–December, 2007.
Rights and permissions
About this article
Cite this article
Konyukhova, Y.G., Kochubei, V.I., Kochubei, D.I. et al. Synthesis of nickel-doped alkali halide microcrystals and their spectral and structural analysis. J Struct Chem 48, 1099–1104 (2007). https://doi.org/10.1007/s10947-007-0176-8
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s10947-007-0176-8