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Intermolecular hydrogen bonds: Comparison of associates in crystals and liquids

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Abstract

The density and sound velocity were measured within wide ranges of temperature for a number of liquids (water, formamide, diols, aliphatic alcohols, cellosolves, ketones), in which various types of H-associate can exist. The temperature dependences of the adiabatic and molar adiabatic compressibility, density, and molar volume are analyzed. The values of the molar adiabatic compressibility permit one to evaluate the dimensionality of H-associates existing in liquids; the values of adiabatic compressibility do not offer this possibility. The terms responsible for the similarity and difference between H-associates in crystals and liquids are discussed.

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Authors and Affiliations

  1. Chemical Faculty, Moscow State University, Moscow

    O. V. Grineva

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  1. O. V. Grineva
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Correspondence to O. V. Grineva.

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__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No. 4, pp. 802–807, July–August, 2007.

Original Russian Text Copyright © 2007 by O. V. Grineva

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Grineva, O.V. Intermolecular hydrogen bonds: Comparison of associates in crystals and liquids. J Struct Chem 48, 753–758 (2007). https://doi.org/10.1007/s10947-007-0115-8

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  • DOI: https://doi.org/10.1007/s10947-007-0115-8

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