Abstract
The X-ray diffraction study of the potassium salt of 2-methoxy-4-dimethylamino-6-dinitromethyl-1,3,5-triazine is carried out. The crystals are triclinic; C7H9N6O −5 ·2K+·2H2O; a = 7.645(7) Å, b = 8.230(7) Å, c = 12.435(9) Å; α = 99.99(8)°, β = 91.52(7)°, γ = 113.86(8)°; V = 701(1) Å3, ρcalc = 1.58 g/cm3, Z = 2, space group P-1. The compound crystallizes as a crystalline hydrate with two water molecules. Two planar fragments of dinitromethyl and 2-methoxy-4-dimethylamino-1,3,5-triazine construct the anion. Their geometrical parameters are explored. The coordination of potassium cations and numerous hydrogen bonds are found which result in the development of a complex 3-D framework.
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Original Russian Text Copyright © 2007 by V. V. Bakharev, A. A. Gidaspov, D. B. Krivolapov, E. V. Mironova, and I. A. Litvinov
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Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No.1, pp.174–177, January–February, 2007.
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Bakharev, V.V., Gidaspov, A.A., Krivolapov, D.B. et al. Crystal and molecular structures of the potassium salt of 2-methoxy-4-dimethylamino-6-dinitromethyl-1,3,5-triazine. J Struct Chem 48, 177–180 (2007). https://doi.org/10.1007/s10947-007-0028-6
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DOI: https://doi.org/10.1007/s10947-007-0028-6