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Synthesis, structure, and properties of [RuNO(NH3)4OH][PtCl4] and [RuNO(NH3)4OH][PdCl4]

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Abstract

Double complex [RuNO(NH3)4OH][PtCl4] (I) and [RuNO(NH3)4OH][PdCl4] (II) salts have been prepared and explored with TGA, IR spectroscopy, powder and single crystals X-ray diffraction. Crystal phases of I and II are isostructural (space group Cmc21) and have the following crystal chemical characteristics: a = 8.106 Å, b = 18.190(3) Å, c = 8.097 Å, V = 1194.0 Å3, Z = 4, ρcalc = 3.077 g/cm3 (I), and a = 8.116 Å, b = 18.135 Å, c = 8.062 Å, V = 1186.5 Å3, Z = 4, ρcalc = 2.600 g/cm3 (II). The product of thermal decomposition of I in inert and hydrogen atmospheres is a substitution solid solution Pt0.5Ru0.5 with the parameter of the FCC unit cell a = 3.856(3) Å. Thermolysis of II affords two-phase mixtures of limited solid solutions of the metals featuring Ru-based HCP and Pd-based FCC cells.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    O. A. Plyusnina, V. A. Emel’yanov, I. A. Baidina, I. V. Korol’kov & S. A. Gromilov

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  1. O. A. Plyusnina
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  2. V. A. Emel’yanov
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  3. I. A. Baidina
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  4. I. V. Korol’kov
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  5. S. A. Gromilov
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__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No.1, pp.114–121, January–February, 2007.

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Plyusnina, O.A., Emel’yanov, V.A., Baidina, I.A. et al. Synthesis, structure, and properties of [RuNO(NH3)4OH][PtCl4] and [RuNO(NH3)4OH][PdCl4]. J Struct Chem 48, 114–121 (2007). https://doi.org/10.1007/s10947-007-0017-9

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  • DOI: https://doi.org/10.1007/s10947-007-0017-9

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