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Synthesis, properties, and structure of dimethylgold(III) complexes [(CH3)2AuI]2 and (CH3)2AuS2CN(C2H5)2

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Abstract

Volatile diethyldithiocarbamate of dimethylgold(III) was prepared by the interaction of dimethylgold(III) iodide with sodium diethyldithiocarbamate. The complex is examined by the elemental analysis, DTA, IR and electronic spectroscopy. The starting dimeric complex [(CH3)2AuI]2 and a novel monomeric volatile gold(III) complex (CH3)2AuS2CN(C2H5)2 with the AuC2S2 coordination core were investigated by single crystal X-ray diffraction for the first time.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    G. I. Zharkova, I. A. Baidina & I. K. Igumenov

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  1. G. I. Zharkova
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  2. I. A. Baidina
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  3. I. K. Igumenov
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Original Russian Text Copyright © 2007 by G. I. Zharkova, I. A. Baidina, and I. K. Igumenov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No.1, pp.108–113, January–February, 2007.

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Zharkova, G.I., Baidina, I.A. & Igumenov, I.K. Synthesis, properties, and structure of dimethylgold(III) complexes [(CH3)2AuI]2 and (CH3)2AuS2CN(C2H5)2 . J Struct Chem 48, 108–113 (2007). https://doi.org/10.1007/s10947-007-0016-x

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  • DOI: https://doi.org/10.1007/s10947-007-0016-x

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