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Synthesis and crystal structure of nitrosoruthenium aquadiammine complex, [Ru(NO)(NH3)2Cl2(H2O)]Cl·H2O

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Abstract

The reaction between [RuNO(NH3)2(NO2)2OH] and an excess of 3 M HCl leads to denitration of the starting complex and precipitation of [Ru(NO)(NH3)2Cl3]. Crystals of the tittle complex have been obtained by evaporation of the mother liquor at ambient temperature. The crystal structure of the product has been determined. The linear nitroso group and a water molecule are coordinated in the trans positions, three nitrogen atoms from NO and NH3 ligands occupy the coordination octahedron face.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    V. A. Emel’yanov, I. A. Baidina, M. A. Il’in & S. A. Gromilov

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  1. V. A. Emel’yanov
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  2. I. A. Baidina
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  3. M. A. Il’in
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  4. S. A. Gromilov
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Original Russian Text Copyright © 2006 by V. A. Emel’yanov, I. A. Baidina, M. A. Il’in, and S. A. Gromilov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 47, No. 2, pp. 385–387, March–April, 2006.

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Emel’yanov, V.A., Baidina, I.A., Il’in, M.A. et al. Synthesis and crystal structure of nitrosoruthenium aquadiammine complex, [Ru(NO)(NH3)2Cl2(H2O)]Cl·H2O. J Struct Chem 47, 380–382 (2006). https://doi.org/10.1007/s10947-006-0311-y

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  • DOI: https://doi.org/10.1007/s10947-006-0311-y

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