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Synthesis and structure of complex compound Rh(III) of (NH4)2[Rh(NO2)3(NH3)(µ-OH)]2 composition

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Abstract

The crystalline structure of a new compound Rh(III) of (NH4)2[Rh(NO2)3(NH3)(µ-OH)]2 composition has been determined. The crystallographic characteristics are H16N10O14Rh2: a = 6.3963(2) Å, b = 9.3701(4) Å, c = 13.6646(5) Å, β = 102.266(1)°, V = 800.28(5) Å3, Z = 2, d calc = 2.432 g/cm3. The distance Rh...Rh in the dimer is 3.200 Å.

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Authors and Affiliations

  1. A. V. Nikolayev Institute of Inorganic Chemistsry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    S. P. Khranenko, I. A. Baidina & S. A. Gromilov

Authors
  1. S. P. Khranenko
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  2. I. A. Baidina
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  3. S. A. Gromilov
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Original Russian Text Copyright © 2006 by S. P. Khranenko, I. A. Baidina, and S. A. Gromilov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 47, No. 2, pp. 380–384, March–April, 2006.

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Khranenko, S.P., Baidina, I.A. & Gromilov, S.A. Synthesis and structure of complex compound Rh(III) of (NH4)2[Rh(NO2)3(NH3)(µ-OH)]2 composition. J Struct Chem 47, 375–379 (2006). https://doi.org/10.1007/s10947-006-0310-z

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  • DOI: https://doi.org/10.1007/s10947-006-0310-z

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