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On interrelation between the internal pressure and the cohesion energy density

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Abstract

The question about the definition of the “internal pressure” concept is being discussed. It is shown that the previously found differential relation between the cohesion energy density and the internal pressure is one of the examples of an absolutely general interrelation between definitely connected differential functions. It is ascertained that the ratio (the internal pressure divided by the cohesion energy density) is a structuresensitive parameter inherent to the calorific (thermal) equation of a liquid state.

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Authors and Affiliations

  1. Saratov State University, Russia

    V. N. Kartsev & K. E. Pankin

  2. Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo

    D. V. Batov

Authors
  1. V. N. Kartsev
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  2. K. E. Pankin
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  3. D. V. Batov
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Original Russian Text Copyright © 2006 by V. N. Kartsev, K. E. Pankin, and D. V. Batov

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 47, No.2, pp. 283–290, March–April, 2006.

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Kartsev, V.N., Pankin, K.E. & Batov, D.V. On interrelation between the internal pressure and the cohesion energy density. J Struct Chem 47, 277–284 (2006). https://doi.org/10.1007/s10947-006-0297-5

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  • DOI: https://doi.org/10.1007/s10947-006-0297-5

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