Abstract
Different approaches to the analysis of the structure of condensed phases are briefly discussed. Introduced definition of the term “supramolecular motif” makes it possible to use this notion as a basis for finding correlations between structural peculiarities of the investigated systems and their properties. It is shown that the study of temperature dependences of the temperature coefficient of compressibility is a convenient way of detecting supramolecular motif (namely, framework of cooperative hydrogen bonds) in dilute aqueous solutions of organic substances.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 47, No. 1, pp. 185–191, January–February, 2006.
Original Russian Text Copyright © 2006 by O. V. Grineva
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Grineva, O.V. Supramolecular motifs in liquids. Aqueous solutions of organic substances. J Struct Chem 47, 186–193 (2006). https://doi.org/10.1007/s10947-006-0285-9
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DOI: https://doi.org/10.1007/s10947-006-0285-9