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Synthesis and X-ray structural study of octa-coordinated hexafluoroacetylacetone hafnium(IV) complex

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Abstract

Hexafluoroacetylacetonate hafnium(IV) complex has been synthesized and studied by X-ray structural analysis. Crystal data for C30H8F36Hf2O14 are: a = 12.957(3) Å, b = 16.687(3) Å, c = 12.398(3) Å, β = 108.97°, space group P21/c, Z = 2, d calc = 2.137 g/cm3, R = 0.047. The molecular structure is built from discrete binuclear molecules of Hf2(OH)2(hfac)6 composition; the Hf...Hf distance in dimer is 3.533 Å. The structural units are connected by van der Waals interactions in the crystal.

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References

  1. K. V. Zherikova, N. B. Morozova, N. V. Kuratieva, et al., Zh. Strukt. Khim., 46, No. 6, 1081–1088 (2005).

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  2. G. M. Sheldrick, SHELX-97. Release 97-1, Univ. Göttingen, Germany (1997).

    Google Scholar 

  3. F. Calderazzo, U. Englert, C. Maichle-Mössmer, et al., Inorg. Chim. Acta., 279, 177–188 (1998).

    Article  Google Scholar 

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    K. V. Zherikova, N. B. Morozova, I. A. Baidina, V. I. Alekseev & I. K. Igumenov

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  1. K. V. Zherikova
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  2. N. B. Morozova
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  3. I. A. Baidina
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  4. V. I. Alekseev
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  5. I. K. Igumenov
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Translated from Zhurnal Strukturnoi Khimii, Vol. 47, No. 1, pp. 87–90, January–February, 2006.

Original Russian Text Copyright © 2006 by K. V. Zherikova, N. B. Morozova, I. A. Baidina, V. I. Alekseev, and I. K. Igumenov

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Zherikova, K.V., Morozova, N.B., Baidina, I.A. et al. Synthesis and X-ray structural study of octa-coordinated hexafluoroacetylacetone hafnium(IV) complex. J Struct Chem 47, 82–86 (2006). https://doi.org/10.1007/s10947-006-0269-9

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  • DOI: https://doi.org/10.1007/s10947-006-0269-9

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