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Crystal structure of oxotitanium(IV) 2,2,6,6-tetramethyl-3,5-heptanedionate

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Abstract

The structure of titanyl dipivalylmethanate TiO(dpm)2 has been studied by X-ray diffraction analysis. The compound has a molecular structure formed by isolated centrosymmetrical dimers [TiO(dpm)2]2; the unit cell contains two structurally related, crystallographically unique binuclear molecules. The Ti...Ti distance in the dimer is 2.73 Å. Crystal data for Ti2C36H76O10: a = 32.477(6) Å, b = 14.409(3) Å, c = 25.630(5) Å; β = 107.82(3)°, space group C2/c, Z = 8, d calc = 1.002 g/cm3.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    N. B. Morozova, A. E. Turgambaeva, I. A. Baidina, V. V. Krysyuk & I. K. Igumenov

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  1. N. B. Morozova
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  2. A. E. Turgambaeva
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  3. I. A. Baidina
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  4. V. V. Krysyuk
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  5. I. K. Igumenov
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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 6, pp.1089–1094, November–December, 2005.

Original Russian Text Copyright © 2005 by N. B. Morozova, A. E. Turgambaeva, I. A. Baidina, V. V. Krysyuk, and I. K. Igumenov

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Morozova, N.B., Turgambaeva, A.E., Baidina, I.A. et al. Crystal structure of oxotitanium(IV) 2,2,6,6-tetramethyl-3,5-heptanedionate. J Struct Chem 46, 1047–1051 (2005). https://doi.org/10.1007/s10947-006-0240-9

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  • DOI: https://doi.org/10.1007/s10947-006-0240-9

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