Abstract
The energy of crystal nucleation from liquid phase was considered, with the following two stages taken into account: (1) the formation of metastable supercooled melt (solution), containing pre-nuclei with intermediate amorphous (quasicrystalline) structure, and (2) the transformation of amorphous clusters into solid crystalline nuclei having different structures. With growth of a nucleus the nucleation energy profile manifests 2–3 maxima corresponding to these stages, and the kinetics of the non-stationary nucleation has five characteristic variations.
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References
Yu. I. Petrov, Clusters and Small Particles [in Russian], Nauka, Moscow (1986).
A. I. Rusanov, Phase Equilibria and Surface Phenomena [in Russian], Khimiya, Leningrad (1967).
E. B. Treivus, Kristallografiya, 47, No. 6, 1144–1148 (2002).
V. A. Polukhin, L. K. Rigmant, and E. V. Potemkina, Proc. X Russian Conf. “Structure and Properties of Metal and Slag Melts,” Vol. 4, Ekaterinburg, YuUrGU (2001), pp. 130/131.
B. O’Malley and I. Snook, Phys. Rev. Lett., 90, No. 8, 085702-1-4 (2003).
I. P. Bazarov and E. V. Gevorkyan, Statistical Theories of Solid and Liquid Crystals [in Russian], MGU, Moscow (1992).
B. I. Kidyarov, Kinetics of Crystallization from Liquid Phase [in Russian], Nauka, Novosibirsk (1979).
I. M. Vasserman, Chemical Deposition from Solutions [in Russian], Khimiya, Leningrad (1980).
F. Faupel, W. Frank, M.-P. Macht, et al., Rev. Modern Phys., 75, No. 1, 237–281 (2003).
H.-S. Nam, N. M. Hwang, B. D. Yu, and J. K. Yoon, Phys. Rev. Lett., 89, No. 27, 275502-1-4 (2002).
V. P. Scripov and V. P. Koverda, Spontaneous Crystallization of Supercooled Liquids [in Russian], Nauka, Moscow (1984).
T. V. Bykova and A. K. Schekin, Koll. Zh., 61, No. 2, 164–171 (1999).
L. Sh. Bazarov, T. N. Drebushchak, V. I. Gordeeva, and F. Kh. Urakaev, J. Cryst. Growth, 206, No. 1, 75–81 (1999).
L. Sh. Bazarov, T. N. Drebushchak, Yu. P. Savintsev, and V. A. Drebushchak, Mendeleev Comm., No. 2, 37–39 (2003).
J. C. Delabrouille, Bull. Soc. Chem. France, 8, No. 8, 3146–3151 (1968).
I. V. Melikhov, E. D. Kozlovskaya, A. M. Kutepov, et al., Concentrated and Saturated Solutions [in Russian], Nauka, Moscow (2002).
A. M. Askhabov, Dokl. Ross. Akad. Nauk, 374, No. 3, 359–361 (2000).
Yu. D. Tre’yakov, Usp. Khim., 72, No. 8, 731–762 (2003).
M. P. Anisimov, ibid, No. 7, 664–705.
B. I. Kidyarov, Korean Cryst. Growth Cryst. Techn., 13, No. 2, 51–55 (2003).
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Original Russian Text Copyright © 2004 by B. I. Kidyarov
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Translated from Zhurnal Strukturnoi Khimii, Vol. 45, Supplement, pp. 32–36, 2004.
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Kidyarov, B.I. Thermodynamics of crystalline nanonucleus formation from liquid phase. J Struct Chem 45 (Suppl 1), S31–S35 (2004). https://doi.org/10.1007/s10947-006-0093-2
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DOI: https://doi.org/10.1007/s10947-006-0093-2