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Atomic ordering as a new way of nanostructure creation in solids

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Abstract

The application of atomic-vacancy ordering for generating nanostructures in non-stoichiometric compounds and substituting solid solutions is considered. The conditions under which a nanostructure is formed in powder and bulk samples and peculiarities of the nanostructure within them are exemplified with non-stoichiometric vanadium carbide VC0.875. The formation of nanostructure in the VC0.875 carbide has been demonstrated to originate from the first order phase transition disorder-order VC0.875 → V8C7 accompanied by an abrupt volume change.

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Ekaterinburg

    A. I. Gusev, A. S. Kurlov, V. N. Lipatnikov & A. A. Rempel

Authors
  1. A. I. Gusev
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  2. A. S. Kurlov
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  3. V. N. Lipatnikov
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  4. A. A. Rempel
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Original Russian Text Copyright © 2004 by A. I. Gusev, A. S. Kurlov, V. N. Lipatnikov, and A. A. Rempel

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Translated from Zhurnal Strukturnoi Khimii, Vol. 45, Supplement, pp. 15–23, 2004.

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Gusev, A.I., Kurlov, A.S., Lipatnikov, V.N. et al. Atomic ordering as a new way of nanostructure creation in solids. J Struct Chem 45 (Suppl 1), S14–S22 (2004). https://doi.org/10.1007/s10947-006-0091-4

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  • DOI: https://doi.org/10.1007/s10947-006-0091-4

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