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Synthesis, structure, and thermal decomposition of a novel one-dimensional chain complex of manganese(II) with 2,2-diphenic acid and 1,10-phenanthroline

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Abstract

A novel one-dimensional (1D) chain coordination polymer [Mn2(2,2′-dipha)2(phen)]n has been synthesized by hydrothermal reaction, and characterized by elemental analysis, IR spectroscopy, TGA, and X-ray diffraction. Orange crystals crystallized in the monoclinic system, space group C2/c with a = 19.393(7) Å, b = 19.183(7) Å, c = 19.729(7) Å, β = 90.826(6)°, V = 7338(5) Å3, Z = 8. In the crystal structure, one manganese atom is six-coordinated with four carboxylate oxygen atoms from one pentadentate 2,2′-dipha ligand and two tetradentate 2,2′-dipha ligands, and with two nitrogen atoms of one phen ligand, giving a slightly distorted octahedral geometry. The other manganese atom is five-coordinated with five oxygen atoms from two tetradentate 2,2′-dipha ligands and two pentadentate 2,2′-dipha ligands and has a trigonal bipyramidal environment. The TGA curve shows that the compound is stable below 310°.

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Authors and Affiliations

  1. Department of Chemistry, Northwest University/Shaanxi Province Key Laboratory of Physicoinorganic Chemistry, Xi’an, 710069, China

    Ren Yan-Wei, Li Jun, Gao Wei-wei & Zhang Feng-Xing

  2. Shaanxi Educational College, Xi’an, 710061, China

    Dang Li-Long

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  1. Ren Yan-Wei
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  2. Dang Li-Long
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  3. Li Jun
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  4. Gao Wei-wei
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  5. Zhang Feng-Xing
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Original Russian Text Copyright © 2005 Ren Yan-Wei, Dang Li-Long, Li Jun, Gao Wei-wei, and Zhang Feng-Xing

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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 2, pp. 361–365, March–April, 2005.

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Yan-Wei, R., Li-Long, D., Jun, L. et al. Synthesis, structure, and thermal decomposition of a novel one-dimensional chain complex of manganese(II) with 2,2-diphenic acid and 1,10-phenanthroline. J Struct Chem 46, 352–357 (2005). https://doi.org/10.1007/s10947-006-0053-x

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  • DOI: https://doi.org/10.1007/s10947-006-0053-x

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