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Crystal and molecular structure of N-(benzylimidazolyl-2)-O-methylcarbamate salts

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Abstract

Single crystal X-ray diffraction has been applied to determine the structure of salts — formate and hydrochloride of N-(benzylimidazolyl-2)-O-methylcarbamate (BMC). The crystal structure of BMC formate is built by a molecule of a base and two formic acid molecules, one of them protonating a BMC molecule. Hydrogen bonds in the crystal form a weakly bound one-dimensional ribbon. BMC hydrochloride crystallizes as dihydrate. Two molecules of crystallization water and Cl ion make a robust H-bonded two-dimensional layer. BMC salts are formed through the protonation of N9 atom.

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Authors and Affiliations

  1. Institute of the Chemistry of Plant Substances, Uzbekistan Academy of Sciences, Tashkent

    K. K. Turgunov, A. G. Tozhiboev & B. Tashkhodzhaev

Authors
  1. K. K. Turgunov
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  2. A. G. Tozhiboev
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  3. B. Tashkhodzhaev
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Original Russian Text Copyright © 2005 by K. K. Turgunov, A. G. Tozhiboev, and B. Tashkhodzhaev

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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 2, pp. 342–347, March–April, 2005.

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Turgunov, K.K., Tozhiboev, A.G. & Tashkhodzhaev, B. Crystal and molecular structure of N-(benzylimidazolyl-2)-O-methylcarbamate salts. J Struct Chem 46, 334–339 (2005). https://doi.org/10.1007/s10947-006-0049-6

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  • DOI: https://doi.org/10.1007/s10947-006-0049-6

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