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Crystal structure and thermal investigation of bis-(1-thenoyl-4,4,4-trifluorobutan-1,3-dionato) lead(II)

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Abstract

Lead(II) complex with thenoyltrifluoroacetone has been prepared and characterized by IR spectroscopy, powder and single crystal X-ray diffraction. Crystal data for PbO4S2F6C16H8: a = 20.457(4) Å, b = 11.292(2) Å, c = 8.409(2) Å; β = 91.37(3)°, space group C2/c, Z = 4, d calc = 2.222 g/cm3. The molecule of the complex is non-planar, average distances Pb-O are 2.384 Å, chelate angle O-Pb-O is 75.0°. The structure is of polymeric chain nature, Pb...Pb separation in the chains being 4.311 Å. The complex Pb(ttf)2 is stable under heating up to 250°C. The compound is less volatile than Cu(ttf)2 or Fe(ttf)3.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Division, Novosibirsk

    I. A. Baidina, P. A. Stabnikov, S. A. Gromilov & I. K. Igumenov

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  1. I. A. Baidina
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  2. P. A. Stabnikov
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  3. S. A. Gromilov
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  4. I. K. Igumenov
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Original Russian Text Copyright © 2005 by I. A. Baidina, P. A. Stabnikov, S. A. Gromilov, and I. K. Igumenov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 2, pp.336–341, March–April, 2005.

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Baidina, I.A., Stabnikov, P.A., Gromilov, S.A. et al. Crystal structure and thermal investigation of bis-(1-thenoyl-4,4,4-trifluorobutan-1,3-dionato) lead(II). J Struct Chem 46, 328–333 (2005). https://doi.org/10.1007/s10947-006-0048-7

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  • DOI: https://doi.org/10.1007/s10947-006-0048-7

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