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Solvation of amides of formic and acetic acids in water-glycerol mixture. Additivity of thermochemical characteristics of solutions

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Abstract

Values of the solution enthalpy of are measured and values of solvation enthalpy are calculated for formamide and N,N-two-substituted methyl-and ethylamides of formic and acetic acids in the mixed solvent: water-glycerol. Enthalpy coefficients of pair interactions between amides and glycerol in aqueous solutions are calculated. The influence of mixture composition and also of a structure and properties of the dissolved compounds on enthalpy characteristics is considered. Within the frames of the offered additive scheme the contributions from the structural fragments of molecules of amides to enthalpy characteristics of solutions are established. It has allowed us to analyze quantitatively the role of nonspecific and specific solvation of amides in solution, to predict the enthalpy of evaporation, solution, solvation, the enthalpy coefficients of pair interactions of experimentally unstudied N-methylformamide, N-ethylformamide, N-methyl-N-ethylformamide, N-methylacetamide, N-ethylacetamide, and N-methyl-N-ethylacetamide in the mixtures of water-glycerol, and also to evaluate the donor numbers of these specified amides.

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References

  1. D. V. Batov, A. M. Zajchikov, V. P. Sljusar, and V. P. Koroljov, Zh. Obsch. Khim., 71, No. 8, 1282–1288 (2001).

    Google Scholar 

  2. R. Skold, J. Suurkuusk, and I. Wadso, J. Chem. Thermodyn., 8, No. 11, 1075–1080 (1976).

    CAS  Google Scholar 

  3. J. N. Spencer, S. K. Berger, C. R. Powell, et al., J. Phys. Chem., 85, No. 9, 1236–1241 (1981).

    Article  CAS  Google Scholar 

  4. A. Rouw and G. Somsen, J. Chem. Soc., Faraday Trans. I., 78, No. 11, 3397–3408 (1982).

    Article  CAS  Google Scholar 

  5. A. H. Sijpkes, A. A. C. M. Oudhuia, G. Somsen, and T. N. Lilley, J. Chem. Thermodyn., 21, No. 4, 343–349 (1989).

    Article  CAS  Google Scholar 

  6. Yu. M. Kessler and N. A. Abakumova, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Technol., XXV, No. 2, 162–167 (1982).

    Google Scholar 

  7. D. V. Batov, A. M. Zajchikov, and N. G. Manin, Zh. Obsch. Khim., 71, No. 6, 909–915 (2001).

    Google Scholar 

  8. D. V. Batov, A. M. Zajchikov, and N. G. Manin, ibid., 72, No. 7, 1114–1121 (2002).

    Google Scholar 

  9. D. V. Batov and A. M. Zajchikov, ibid., 73, No. 4, 545–552 (2003).

    Google Scholar 

  10. V. A. Klimova, The Main Micromethods of Organic Compounds Analysis [in Russian], Khimia, Moscow (1967).

    Google Scholar 

  11. D. V. Batov, V. P. Korolyov, and G. A. Krestov, Thermochim. Acta., 169, No. 1, 69–80 (1990).

    Article  Google Scholar 

  12. W. K. Stephenson and R. Fuchs, Can. J. Chem., 63, No. 2, 336–341 (1985).

    Article  CAS  Google Scholar 

  13. R. Fuchs and W. K. Stephenson, ibid., 349–352.

  14. V. P. Belousov and M. Yu. Panov, Thermodynamics of Aqueous Solutions of Non Electrolytes [in Russian], Chemistry, Leningrad (1983).

    Google Scholar 

  15. G. Della Gatta, L. Stradella, and P. Venturello, J. Sol. Chem., 10, No. 3, 209–220 (1981).

    Article  CAS  Google Scholar 

  16. F. Rocha and M. Bastos, ibid., 26, No. 10, 989–996 (1997).

    CAS  Google Scholar 

  17. V. M. Tatievskii, Theory of Physical and Chemical Properties of Molecules and Substances [in Russian], Mosk. Gos. Univ. (1987).

  18. J. J. Savage and R. H. Wood, J. Sol. Chem., 5, 733–750 (1976).

    Article  CAS  Google Scholar 

  19. J. Konicek and I. Wadso, Acta Chem. Scan., 25, 1541–1546 (1971).

    Article  CAS  Google Scholar 

  20. A. M. Zajchikov and N. G. Manin, Zh. Obsch. Khim., 71, No. 5, 726–735 (2001).

    Google Scholar 

  21. S. Cabani, P. Gianni, V. Mollica, and L. Lepori, J. Sol. Chem., 10, 563–595 (1981).

    Article  CAS  Google Scholar 

  22. G. Barone, G. Castronuovo, G. Della Gatta, et al., Fluid Phase Equil., 21, No. 1/2, 157–164 (1985).

    Article  CAS  Google Scholar 

  23. R. Sabbah, R. Chastel, and M. Laffitte, Thermochim. Acta., 5, No. 1, 117–127 (1972).

    Article  CAS  Google Scholar 

  24. Yu. M. Kessler and A. L. Zaitsev, Solvophobic Effects, Khimia, Leningrad (1989).

    Google Scholar 

  25. Y. Marcus, Chem. Soc. Rev., 22, No. 6, 409–416 (1993).

    Article  CAS  Google Scholar 

  26. V. Gutmann, Chemistry of Coordination Compounds in Nonaqueous Solution, Springer-Verlag Viena, New York (1968).

    Google Scholar 

  27. E. M. Arnett, Quantitative Comparison of Weak Organic Bases. Modern Problems of Physical Organic Chemistry [Russian translation], Mir, Moscow (1967).

    Google Scholar 

  28. Yu. M. Kessler, P. R. Fomicheva, and N. M. Alpatova, Zh. Strukt. Khim., 13, No. 3, 517–519 (1972).

    CAS  Google Scholar 

  29. A. K. Ljashchenko, V. S. Har’kin, A. S. Lileev, and V. S. Goncharov, Zh. Fiz. Khim., 66, No. 8, 2256–2261 (1992).

    Google Scholar 

  30. N. D. Devjatkov, O. V. Betskij, V. A. Zavizion, et. al., Dokl. Akad. Nauk SSSR, 264, No. 6, 1409–1411 (1982).

    Google Scholar 

  31. W. G. McMillan and J. E. Mayer, J. Phys. Chem., 13, No. 1, 276–305 (1945).

    CAS  Google Scholar 

  32. J. E. Desnoyers, G. Perron, L. Avedikian, and J. P. Morel, J. Sol. Chem., 5, No. 9, 631–644 (1976).

    Article  CAS  Google Scholar 

  33. P. J. Cheek and T. N. Lilley, J. Chem. Soc., Faraday Trans. I., 84, No. 6, 1927–1940 (1988).

    Article  CAS  Google Scholar 

  34. A. Zielenkiewicz, Thermochim. Acta., 79, No. 1, 371–376 (1984).

    Article  CAS  Google Scholar 

  35. J. P. Grolier, J. J. Spitzer, R. H. Wood, and I. R. Tasker, J. Sol. Chem., 14, No. 6, 393–405 (1985).

    Article  CAS  Google Scholar 

  36. I. R. Tasker and R. H. Wood, ibid., 11, No. 5, 295–308 (1982).

    CAS  Google Scholar 

  37. S. K. Suri, J. J. Spitzer, R. H. Wood, et al., ibid., 14, No. 11, 781–794 (1985).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Science, Ivanovo

    D. V. Batov

  2. Ivanovo State University of Chemical Technology, Ivanovo

    D. D. Batov

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  1. D. V. Batov
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  2. D. D. Batov
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Original Russian Text Copyright © 2005 by D. V. Batov and D. D. Batov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 2, pp. 293–302, March–April, 2005.

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Batov, D.V., Batov, D.D. Solvation of amides of formic and acetic acids in water-glycerol mixture. Additivity of thermochemical characteristics of solutions. J Struct Chem 46, 285–294 (2005). https://doi.org/10.1007/s10947-006-0042-0

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  • DOI: https://doi.org/10.1007/s10947-006-0042-0

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