Abstract
According to IR spectroscopy data and ab initio quantum chemical computations, a novel representative of intracomplex organosilicon compounds — N-(trifluorosilylmethyl)succinimide (I) possesses an anomalously high sensitivity to medium effects. Coordination bond O→Si of the compound I is strong in the solid phase and polar medium, and weak in its isolated molecules. Geometric parameters calculated for the molecule I in polar medium correspond to X-ray diffraction data.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
V. F. Sidorkin, E. F. Belogolova, and V. A. Pestunovich, J. Mol. Struct. (Theochem), 538, Nos. 2/3, 59–65 (2001).
E. F. Belogolova and V. F. Sidorkin, ibid., 668, Nos. 2/3, 139–145 (2004).
E. F. Belogolova and V. F. Sidorkin, Izv. Ross. Akad. Nauk, Ser. Khim., No. 7, 1392–1396 (2003).
D. Kost and I. Kalichman, The Chemistry of Organic Silicon Compounds, Z. Rappoport and Y. Apeloig (eds.), Wiley, New York (1998).
Yu. L. Frolov and M. G. Voronkov, Metalloorg. Khim., 3, No. 5, 1038–1047 (1990).
G. A. Gavrilova, T. N. Aksamentova, Yu. L. Frolov, et al., ibid, No. 6, 1266–1270 (1990).
M. G. Voronkov, É. A. Zel’bst, A. A. Kashaev, et al., Dokl. Ross. Akad. Nauk, 393, No., 4, 493–496 (2003).
M. G. Voronkov, N. N. Chipanina, B. A. Shainyan, et al., ibid, 394,No. 2, 203–206 (2004).
M. G. Voronkov, Izv. Ross. Akad. Nauk, Ser. Khim., No. 12, 2664–2681 (1991).
G. A. Gavrilova, T. N. Aksamentova, Yu. L. Frolov, et al., Metalloorg. Khim., 3, No. 6, 1266–1271 (1990).
J. I. Musher, Angew. Chem. Int. Enql., 8, 54–70 (1969).
V. A. Pestunovich, S. A. Kirpichenko, M. G. Voronkov, The Chemistry of Organic Silicon Compounds, Wiley, New York (1998).
T. Woldbaek, P. Klaeboe, and D. H. Christensen, Acta Chem. Scand., A30, No. 7, 531–539 (1976).
B. A. Stamboliyska, Y. I. Binev, V. B. Radomirska, et al., J. Mol. Struct., 516, Nos. 2/3, 237–245 (2000).
T. Woldbaek, P. Klaeboe, and D. H. Christensen, Acta Chem. Scand., A30, No. 7, 547–554 (1976).
C. Fayat and A. Foucaud, Bull. Soc. Chim. France, No. 12, 4501–4510 (1970).
T. Matsuo, Bull. Chem. Soc. Jpn., 37, No. 12, 1844–1848 (1964).
M. J. Frisch, G. W. Trucks, H. B. Schlegel, et al., Gaussian-98, Gaussian, Inc., Pittsburgh PA (1998).
Author information
Authors and Affiliations
Additional information
Original Russian Text Copyright © 2005 by T. N. Aksamentova, M. G. Voronkov, O. M. Trofimova, N. N. Chipanina, Yu. I. Bolgova N. F. Chernov, É. A. Zel’bst, and V. K. Turchaninov
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 2, pp. 257–261, March–April, 2005.
Rights and permissions
About this article
Cite this article
Aksamentova, T.N., Voronkov, M.G., Trofimova, O.M. et al. Unusual lability of intramolecular coordination bond O→Si N-(trifluorosilylmethyl)succinimide. J Struct Chem 46, 248–252 (2005). https://doi.org/10.1007/s10947-006-0038-9
Received:
Issue Date:
DOI: https://doi.org/10.1007/s10947-006-0038-9