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Synthesis and structure of [Ni(dien)2]3[W4S4(CN)2]·20H2O and [Cu(dien)(Hdien)]2[W4S4(CN)12]·8H2O

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Abstract

[Ni(dien)2]3[W4S4(CN)12]·20H2O and [Cu(dien)(Hdien)]2[W4S4(CN)12]·8H2O were obtained by evaporating water-ammonia solutions containing K6[W4S4(CN)12]·2H2O·2CH3OH, diethylene triamine, and NiCl2·6H2O or CuCl2·6H2O. The crystals of the complex compounds were obtained within 3 days. The complex compounds were characterized by IR spectroscopy and by XRD and elemental analysis. XRD data for the complex [Ni(dien)2]3[W4S4(CN)12]·20H2O are: triclinic system, \(P\overline 1 \), a = 14.671(2) Å, b = 16.448(3) Å, c = 19.814(3) Å, α = 67.841(3)°, β = 68.996(3)°, γ = 67.527(3)°, V = 3961.6(11) Å3, Z = 2; for the complex [Cu(dien)(Hdien)]2[W4S4(CN)12]·8H2O: monoclinic system, C2/c, a = 37.4290(1) Å, b = 17.7370(1) Å, c = 25.7370(2) Å, β = 105.3840(2)°, V = 16474.02(16) Å3, Z = 12.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    I. V. Kalinina, D. G. Samsonenko & V. P. Fedin

  2. A. N. Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, Moscow

    Z. A. Starikova, A. A. Korlyukov & M. Yu. Antipin

  3. Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw

    J. Lipkowski

Authors
  1. I. V. Kalinina
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  2. D. G. Samsonenko
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  3. Z. A. Starikova
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  4. A. A. Korlyukov
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  5. J. Lipkowski
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  6. V. P. Fedin
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  7. M. Yu. Antipin
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Original Russian Text Copyright © 2005 by I. V. Kalinina, D. G. Samsonenko, Z. A. Starikova, A. A. Korlyukov, J. Lipkowski, V. P. Fedin, and M. Yu. Antipin

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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 1, pp. 139–148, January–February, 2005.

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Kalinina, I.V., Samsonenko, D.G., Starikova, Z.A. et al. Synthesis and structure of [Ni(dien)2]3[W4S4(CN)2]·20H2O and [Cu(dien)(Hdien)]2[W4S4(CN)12]·8H2O. J Struct Chem 46, 137–146 (2005). https://doi.org/10.1007/s10947-006-0020-6

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  • DOI: https://doi.org/10.1007/s10947-006-0020-6

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