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Synthesis, crystal structure, and properties of [Rh(NH3)5Cl][ReBr6]

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Abstract

A binary complex salt [Rh(NH3)5Cl][ReBr6] has been synthesized and investigated by X-ray diffraction analysis. Crystal data: a = 8.541(5) Å, b = 12.015(6) Å, c = 16.496(9) Å; α = 73.695(10)°, β = 89.746(9)°, γ = 89.676(9)°, V = 1624.7 Å3, space group \(P\overline 1 \), Z = 4, D x = 3.635 g/cm3, R = 0.12. It is shown that the product of thermolysis of the salt in the atmosphere of hydrogen and helium is a solid solution Rh0.5Re0.5 with hcp cell parameters a = 2.731(5) Å and c = 4.368(7) Å.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    K. V. Yusenko, S. A. Gromilov, I. A. Baidina, I. V. Korolkov & S. V. Korenev

Authors
  1. K. V. Yusenko
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  2. S. A. Gromilov
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  3. I. A. Baidina
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  4. I. V. Korolkov
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  5. S. V. Korenev
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Original Russian Text Copyright © 2005 by K. V. Yusenko, S. A. Gromilov, I. A. Baidina, I. V. Korolkov, and S. V. Korenev

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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 1, pp. 111–117, January–February, 2005.

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Yusenko, K.V., Gromilov, S.A., Baidina, I.A. et al. Synthesis, crystal structure, and properties of [Rh(NH3)5Cl][ReBr6]. J Struct Chem 46, 109–115 (2005). https://doi.org/10.1007/s10947-006-0016-2

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  • DOI: https://doi.org/10.1007/s10947-006-0016-2

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