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Novel Cyanide-Bridged Three-Dimensional Coordination Polymer Derived from an Octahedral Rhenium Cluster [Re6Te8(CN)6]4−: Synthesis and Crystal Structure of [{Mn(H2O)2(DMF)} 2Re6Te8(CN)6]·2H2O

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Abstract

The reaction of a water solution of K4Re6Te8(CN)6 with a solution of Mn(NO3)2 in 0.02M hydrochloric acid in the presence of DMF gave crystals of a cluster rhenium complex [{ Mn(H2O)2(DMF)}2Re6Te8(CN)6]·2H2O. The structure of the compound was determined by single crystal X-ray diffraction (a = 12.6679(9) Å, b = 17.4524(12) Å, c = 9.7882(6) Å, β = 105.570(6)°, V = 2084.6(3) Å3, Z = 2, space group P21/n, R = 0. 0389). In the complex, the [Re6Te8(CN)6]4− cluster anions are linked to Mn2+ cations by the cyanide bridges, the manganese cations being additionally coordinated by the DMF molecule and two water molecules. The neighboring clusters are joined by Re-C-N-Mn bridges into a three-dimensional framework possessing cavities filled with doubly disordered water molecules.

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REFERENCES

  1. Perrin and M. Sergent, New J. Chem., 12, 337–356 (1988).

    CAS  Google Scholar 

  2. V. E. Fedorov, A. V. Mischenko, and V. P. Fedin, Usp. Khim., 54, 694–719 (1985).

    CAS  Google Scholar 

  3. T. Saito, Adv. Inorg. Chem., 44, 45–91 (1997).

    CAS  Google Scholar 

  4. Yu. V. Mironov and V. E. Fedorov, Izv. Akad. Nauk. Ser. Khim., 43, 529–539 (2002).

    Google Scholar 

  5. J.-C. P. Gabriel, K. Boubekeur, S. Uriel, and P. Batail, Chem. Rev., 101, 2037–2066 (2001).

    Article  CAS  PubMed  Google Scholar 

  6. T. Saito, J. Chem. Soc., Dalton Trans., 97–105 (1999).

  7. V. E. Fedorov, N. G. Naumov, Yu. V. Mironov, et al., Zh. Strukt. Khim., 43, 721–736 (2002).

    Google Scholar 

  8. Y. V. Mironov, A. V. Virovets, V. E. Fedorov, et al., Polyhedron, 14, 3171–3173 (1995).

    Article  CAS  Google Scholar 

  9. A. Slougui, Y. V. Mironov, A. Perrin, and V. E. Fedorov, Croat. Chem. Acta, 68, 885–890 (1995).

    CAS  Google Scholar 

  10. Y. V. Mironov, J. A. Cody, T. A. Albrecht-Schmitt, and J. A. Ibers, J. Am. Chem. Soc., 119, 493–498 (1997).

    Article  CAS  Google Scholar 

  11. N. G. Naumov, A. V. Virovets, and V. E. Fedorov, Zh. Strukt. Khim., 41, 609–638 (2000).

    Google Scholar 

  12. Yu. V. Mironov, O. Oeckler, A. Simon, and V. E. Fedorov, Eur. J. Inorg. Chem., 2751–2753 (2001).

  13. Yu. V. Mironov, V. E. Fedorov, I. Ijjaali, and J. A. Ibers, Inorg. Chem., 40, 6320–6323 (2001).

    Google Scholar 

  14. N. G. Naumov, Yu. I. Mironov, Yu. V Mironov, et al, Zh. Neorg. Khim., 43, 1916–1920 (1998).

    Google Scholar 

  15. G. M. Sheldrick, SHELX-97, Release 97-2, Univ. Gottingen (1997).

  16. H. Imoto, N. G. Naumov, A. V. Virovets, et al., Zh. Strukt. Khim., 39, 885–893 (1998).

    Google Scholar 

  17. N. G. Naumov, S. B. Artemkina, A. V. Virovets, and V. E. Fedorov, J. Solid State Chem., 153, 195–204 (2000).

    Article  CAS  Google Scholar 

  18. N. G. Naumov, A. V. Virovets, M. N. Sokolov, et al., Angew. Chem. Int. Ed. Engl., 37, 1943–1945 (1998).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    Yu. V. Mironov, S. F. Solodovnikov & V. E. Fedorov

  2. Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    Yu. V. Gatilov

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  1. Yu. V. Mironov
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  2. S. F. Solodovnikov
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  3. V. E. Fedorov
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  4. Yu. V. Gatilov
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Original Russian Text Copyright © 2004 by Yu. V. Mironov, S. F. Solodovnikov, V. E. Fedorov, and Yu. V. Gatilov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 918–922, September–October, 2004.

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Mironov, Y.V., Solodovnikov, S.F., Fedorov, V.E. et al. Novel Cyanide-Bridged Three-Dimensional Coordination Polymer Derived from an Octahedral Rhenium Cluster [Re6Te8(CN)6]4−: Synthesis and Crystal Structure of [{Mn(H2O)2(DMF)} 2Re6Te8(CN)6]·2H2O. J Struct Chem 45, 874–878 (2004). https://doi.org/10.1007/s10947-005-0072-z

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  • DOI: https://doi.org/10.1007/s10947-005-0072-z

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