Skip to main content
SpringerLink
Log in

Crystal structure of 1-(2-pyridiniomethyl)-2,4-bis(phenylsulfonyl)benzene bromide

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The crystal structure of 1-(2-pyridiniomethyl)-2,4-bis(phenylsulfonyl)benzene bromide, (C24H20NO4S2)+. Br− (I) has been investigated by X-ray diffraction (XRD)analysis. The triclinic structure of I (space group P1, a = 7.863 Å, b = 8.350 Å, c = 9.043 Å, α = 94.00°, β = 97.81°, γ = 104.62°, Z = 1) was solved by direct methods and refined by full-matrix least-squares analysis in an anisotropic approximation to R = 0.048 for all 4570 reflections collected (CAD-4 automatic diffractometer, λCuK α). The geometrical parameters of the organic cation were determined with a sufficient degree of accuracy. The crystal structure of I involves a very strong interionic hydrogen bond N+-H⋅⋅⋅Br−.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. P. Coppens, L. Leiserowitz, and D. Rabinovich, Acta Crystallogr., 18, No.6, 1035–1038 (1965).

    Google Scholar 

  2. G. M. Sheldrick, The SHELX-97 Manual, Univ. Göttingen (1997).

  3. H. D. Flack, Acta Crystallogr., A39, No.6, 876–881 (1983).

    Google Scholar 

  4. International Tables for Crystallography, Vol. C, Kluwer, Dordrecht (1992).

  5. F. H. Allen., O. Kennard, D. G. Watson, et al., J. Chem. Soc., Perkin Trans., 2, No.12, S1–S19 (1987).

    Google Scholar 

  6. A. Domenicano, A. Vaciago, and C. A. Coulson, Acta Crystallogr., B31, No.6, 1630–1641 (1975).

    Google Scholar 

  7. A. Bondi, J. Phys. Chem., 68, No.3, 441–451 (1964).

    Google Scholar 

  8. E. A. Meyer, R. K. Castellano, and F. Diederich, Angew. Chem. Int. Ed., 42, No.11, 1210–1250 (2003).

    Google Scholar 

  9. R. Taylor and O. Kennard, J. Am. Chem. Soc., 104, No.19, 5063–5070 (1982).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics Problems, Russian Academy of Sciences, Chernogolovka

    A. N. Chekhlov

Authors
  1. A. N. Chekhlov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text Copyright © 2004 by A. N. Chekhlov

Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 4, pp. 759–763, July–August, 2004.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chekhlov, A.N. Crystal structure of 1-(2-pyridiniomethyl)-2,4-bis(phenylsulfonyl)benzene bromide. J Struct Chem 45, 724–728 (2004). https://doi.org/10.1007/s10947-005-0051-4

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10947-005-0051-4

Keywords

Search

Navigation