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Synthesis and structure of a three-dimensional coordination polymer [Ag3hmt3(μ3-btc)]·5H2O

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Abstract

A new coordination polymer [Ag3hmt3(μ3-btc)]·5H2O (1 )(hmt = hexamethylenetetramine, btc = 1,3,5-benzenetricarboxyl)has been successfully synthesized. Crystal data: P21/a , a = 11.9906(2) Å, b = 17.3689(2) Å, c = 16.96100(10) Å, β = 101.9820(14)°, V = 3455.40(7) Å3, Z = 4, Dc = 2.002 mg/m3. In the hexagonal structure of the Ag-hmt unit, each Ag-hmt unit comprises three Ag atoms and three hmt ligands. The μ3-btc ligands bridge the adjacent two-dimensional honeycomb-like Ag-hmt layers to form three-dimensional networks. Structural analysis shows that hydrogen bonds play a key role for the structural stability of the compounds.

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Authors and Affiliations

  1. Department of Chemical Physics, University of Science and Technology of China, Hefei, P. R. China

    Shoubo Qin, Sheming Lu, Yanxiong Ke, Jianmin Li & Shuxi Zhou

  2. State Key Laboratory of Structural Chemistry, Fujian Institute of Structural Research, Chinese Academy of Science, Fuzhou, P. R. China

    Xintao Wu & Wenxin Du

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  1. Shoubo Qin
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  2. Sheming Lu
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  3. Yanxiong Ke
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  4. Jianmin Li
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Original Russian Text Copyright © 2004 by Shoubo Qin, Sheming Lu, Yanxiong Ke, Jianmin Li, Shuxi Zhou, Xintao Wu, and Wenxin Du

Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 3, pp. 566–571, May–June 2004.

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Qin, S., Lu, S., Ke, Y. et al. Synthesis and structure of a three-dimensional coordination polymer [Ag3hmt3(μ3-btc)]·5H2O. J Struct Chem 45, 541–546 (2004). https://doi.org/10.1007/s10947-005-0027-4

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  • DOI: https://doi.org/10.1007/s10947-005-0027-4

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