Abstract
In 1-methyl-1,2-dinitroguanidine, the nitroguanyl group has planar geometry with an intramolecular hydrogen bond, although the conformation of the whole molecule is slightly nonplanar. Because of π- electron density delocalization, the C-N, N-N, and N-O bond lengths are intermediate between the corresponding values for the single and double bonds. The distinction of the crystal structure is the absence of intermolecular hydrogen bonds.
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Original Russian Text Copyright © 2004 by A. D. Vasiliev, A. M. Astakhov, M. S. Molokeev, L. A. Kruglyakova, and R. S. Stepanov
Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 3, pp. 558–561, May–June 2004.
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Vasiliev, A.D., Astakhov, A.M., Molokeev, M.S. et al. Crystal and molecular structure of 1-methyl-1,2-dinitroguanidine. J Struct Chem 45, 532–536 (2004). https://doi.org/10.1007/s10947-005-0025-6
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DOI: https://doi.org/10.1007/s10947-005-0025-6