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Synthesis and crystal structure of copper halide complexes with triethylallylammonium (teaa) chloride: [(teaa)Cu I3 Cl4], [(teaa)Cu I3 Br3.86Cl0.14], and (teaa)2CuIICl4

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Abstract

The results of X-ray diffraction analysis of novel triethylallylammonium chloride compounds with copper(I) chloride, copper(I) bromide, and copper(II) chloride are reported. The [(CH3CH2)3(CH2=CHCH2xN]Cu I3 Cl4 and [(CH3CH2)3(CH2=CHCH2Cu I3 Br3.86)Cl0.14 π-complexes are isostructural: space group P21/a; a= 17.58(1) Å, b = 12.059(8)Å, c = 7.184(4) Å, β = 98.37(5)° and a = 17.972(9) Å, b=12.479(8) Å, c = 7.290(5) Å, β = 98.81(5)°, respectively. η2-Coordination of the copper atom by the olefinic bond plays a key role in the structural ordering of the tetraalkylammonium cation. In contrast, the structure of {(CH3CH2)3x(CH2=CHCH2)N}2CuIICl4 (P42/nmc; a = 8.839(3) Å, c =15.660(9) Å) follows the ionic salt pattern.

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REFERENCES

  1. L. G. Akselrud Yu. M. Gryn P. Yu. Zavalii et al. (1989) Abstr. 12th Eur. Crystallography Meeting USSR Academy of Sciences Moscow 155

    Google Scholar 

  2. V. V. Olijnik E. A. Goreshnik (1994) Zh. Strukt. Khim. 35 IssueID5 109–119

    Google Scholar 

  3. V. V. Olijnik M. G. Myskiv M. D. Mazus et al. (1992) Zh. Strukt. Khim. 33 IssueID1 121–125

    Google Scholar 

  4. V. V. Olijnik M. G. Myskiv V. K. Pecharskii (1993) Zh. Strukt. Khim. 34 IssueID6 43–48

    Google Scholar 

  5. Ya. E. Filinchuk M. G. Myskiv (2000) Koordinats. Khim. 26 IssueID3 229–234

    Google Scholar 

  6. S. Andersson S. Jagner (1985) Acta Chem. Scand. A39 423–426

    Google Scholar 

  7. S. Andersson S. Jagner (1989) Acta Chem. Scand. A43 39–43

    Google Scholar 

  8. J. E. Huheey (1983) Inorganic Chemistry, Principles of Structure and Reactivity Harper and Row New York

    Google Scholar 

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Authors and Affiliations

  1. Ukrainian State University of Forestry and Wood Technology, Ukraine

    T. P. Lenkivska

  2. Ivan Franko Lvov National University, Ukraine

    V. V. Olijnik & V. N. Davydov

Authors
  1. T. P. Lenkivska
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  2. V. V. Olijnik
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  3. V. N. Davydov
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Original Russian Text Copyright © 2004 by L. M. Babkov, I. I. Gnatyuk, G. A. Puchkovskaya, and S. V. Trukhachev

Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 3, pp. 398–405, May–June, 2004.

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Lenkivska, T.P., Olijnik, V.V. & Davydov, V.N. Synthesis and crystal structure of copper halide complexes with triethylallylammonium (teaa) chloride: [(teaa)Cu I3 Cl4], [(teaa)Cu I3 Br3.86Cl0.14], and (teaa)2CuIICl4 . J Struct Chem 45, 502–508 (2004). https://doi.org/10.1007/s10947-005-0020-y

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  • DOI: https://doi.org/10.1007/s10947-005-0020-y

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