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Crystal structure of copper(II) bis-hexafluoroacetylacetonate

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Abstract

An X-ray diffraction investigation has performed for copper(II) bis-hexafluoroacetylacetonate (Bruker AXS P4 automatic diffractometer, MoK α radiation, t = −25°C). Crystal data for C10H2CuF12O4: a = 5.530(1) Å, b = 6.038(1) Å, c = 11.266(2) Å, α = 95.948(3)°, β = 101.743(3)°, γ = 92.298(3)°, space group; P1, V = 365.6(1) Å3, Z = 1, d calc = 2.169 g/cm3. The square-planar environment of the copper atom (Cu-Oav 1.912 Å, ∠O-Cu-Oav 93°) is completed to bipyramidal by two fluorine atoms of the neighboring molecules, Cu...F 2.71 Å and 2.75 Å.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    S. A. Gromilov, I. A. Baidina & P. A. Stabnikov

  2. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    G. V. Romanenko

Authors
  1. S. A. Gromilov
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  2. I. A. Baidina
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  3. P. A. Stabnikov
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  4. G. V. Romanenko
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Original Russian Text Copyright © 2004 by S. A. Gromilov, I. A. Baidina, P. A. Stabnikov, and G. V. Romanenko

Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 3, pp. 502–507, May–June 2004.

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Gromilov, S.A., Baidina, I.A., Stabnikov, P.A. et al. Crystal structure of copper(II) bis-hexafluoroacetylacetonate. J Struct Chem 45, 476–481 (2004). https://doi.org/10.1007/s10947-005-0016-7

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  • DOI: https://doi.org/10.1007/s10947-005-0016-7

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