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Specific Features of Thermochemical and Rate Processes on Destruction of Chemical Munnition

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Journal of Russian Laser Research Aims and scope

Abstract

The prospects for using laser beam technologies for disposal of chemical munnition are considered within the framework of works on the destruction of chemical weapons. A single-stage technology of destruction of the subelements of chemical munnition in molten aluminum inside a furnace-armored chamber is described. The rate and the thermochemical processes proceeding during the thermal decomposition of the components of an munnition subelement are analyzed in detail and the yield of secondary harmful substances is calculated. All sources of the secondary harmful substances formed during the thermal treatment of the cases of air chemical munnition are revealed. The chemical composition of the medium inside the heat chamber during treatment of cases of various types of munnition is calculated. The requirements for the purification system of waste gases are determined on the basis of a detailed analysis of all nomenclature of the cases to be treated.

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References

  1. V. M. Koshelev, V. A. Zhdanov, A. A. Shuvalov, et al., “American developments of the destruction techniques of chemical weapons,” in: Yu. M. Arskii (Ed.), Chemical Weapons. Ecologic Problems of Destruction [in Russian], VINITI, Moscow (1998), p. 36.

    Google Scholar 

  2. V. M. Koshelev, V. A. Zhdanov, A. A. Shuvalov, et al., Ros. Khim. Zh., 39, 31 (1995).

    Google Scholar 

  3. C. R. Peterson, “Chemical warfare and weapons disposal experience in the United States,” in: N. T. Schulte (Ed.), Dismantlement and Destruction of Chemical, Nuclear and Conventional Weapons, Kluwer Academic Publishers, Dordrecht, Boston (1997), p. 135.

    Google Scholar 

  4. V. Starrock, “Destrucrion of old chemical weapons in Munster,” in: N. T. Schulte (Ed.), Dismantlement and Destruction of Chemical, Nuclear and Conventional Weapons, Kluwer Academic Publishers, Dordrecht, Boston (1997), p. 65.

    Google Scholar 

  5. Review of Systemization of the Tooele Chemical Agent Disposal Facility, Academic Press, Washington (1996).

  6. Tooele Chemical Agent Disposal Facility: Update on National Research Council Recommendations, Academic Press, Washington (1999).

  7. G. Pirson, Ros. Khim. Zh., 39, 113 (1995).

    Google Scholar 

  8. Disposal of Chemical weapons: Alternative Technologies-Background Paper, OTA-BP-0-95, U. S. Government Printing Office, Washington (1992).

  9. B. G. Trusov, Method and Algorithm of Calculation of the Equilibrium Composition and Properties of Multicomponent Heterogeneous Systems [in Russian], Bauman State Technical University Publishers, Moscow (2000).

    Google Scholar 

  10. B. G. Trusov, Description of the Program of Thermodynamic Calculation of Arbitrary Heterogeneous Systems and their Thermodynamic and Transport Properties [in Russian], Bauman State Technical University Publishers, Moscow (2000).

    Google Scholar 

  11. All-Union state standard 12.1.005-88* General Hygiene and Sanitary Requirements on the Air of Working Zones [in Russian].

  12. M. K. Denison, C. J. Montgomery, A. F. Sarofin, et al., “Computational modeling of a chemical demilitarization deactivation furnace system,” IT3.03 Conference (Orlando, USA, May 12–16, 2003).

  13. P. A. Glaude, H. J. Curran, W. J. Pitz, and C. K. WestBrook, “Kinetic study of the combustion of organophosphorus compounds,” 29th Int. Symp. on Combustion (Japan, 2002).

  14. I. D. Gridin, A. Ya. Fedorov, and S. P. Gridina, “Method for Destruction of Highly Toxic Organic Compounds,” Patent of the Russian Federation No. 2113874 (1995).

  15. V. N. Aleksandrov, Toxic Agents [in Russian], Voenizdat, Moscow (1969).

    Google Scholar 

  16. All-Union Standards of Paint-Coat Consumption [in Russian], published by the Research and Production Corporation “Lakokraspokrytie,” Cheboksary (1987).

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Koren’kov, V.V., Kulagin, Y.A., Tokmakov, A.V. et al. Specific Features of Thermochemical and Rate Processes on Destruction of Chemical Munnition. J Russ Laser Res 26, 328–345 (2005). https://doi.org/10.1007/s10946-005-0026-0

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  • DOI: https://doi.org/10.1007/s10946-005-0026-0

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